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- W2015687046 abstract "The rate constants for reactions (4) and (5) were determined at room temperature by pulsed laser photolysis and time resolved mass spectrometry. A description of the experimental setup is given. CFCl2O2 radicals were generated by photolysis of CFCl3 at 193 nm in the presence of an excess of oxygen, using an excimer laser. The rate constant for reaction (4), determined under different experimental conditions is: The rate constant of reaction (5) was determined in the pressure range of 1–12 torr, using oxygen as the buffer gas. The reaction is in its fall-off region and the parameters determined by using the semiempirical method of Troe, taking Fc = 0.6 are: The value of k(∞) is obtained from the low-pressure measurements and therefore the uncertainty on the actual high-pressure limit is higher than the error limits quoted above. The results are compared with those reported for similar reactions." @default.
- W2015687046 created "2016-06-24" @default.
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- W2015687046 date "1984-09-01" @default.
- W2015687046 modified "2023-09-25" @default.
- W2015687046 title "Determination of the rate constants for the reactions of CFCl2O2 radical with NO and NO2 by laser photolysis and time resolved mass spectrometry" @default.
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- W2015687046 doi "https://doi.org/10.1002/kin.550160907" @default.
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