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- W2015691851 abstract "Mechanism of the oxidative dimerization of DTF (dithiafulvenes) to form TTF vinylogues (tetrathiafulvalenes) has been investigated by cyclic voltammetry at low and high scan rates for a series of substituted DTF. It involves first the formation of the cation radical which couples to form the protonated dication. This dication slowly deprotonates to give the final TTF (k = 0.5−1 s-1). The dimerization rate constant was found to be in the range of kdim = (2−4) × 108 L mol-1 s-1 and not vary much with the nature of the substituent." @default.
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- W2015691851 date "2010-08-04" @default.
- W2015691851 modified "2023-09-30" @default.
- W2015691851 title "ChemInform Abstract: Mechanism of Dimerization of 1,4-Dithiafulvenes into TTF Vinylogues." @default.
- W2015691851 cites W2951334061 @default.
- W2015691851 doi "https://doi.org/10.1002/chin.199649036" @default.
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