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- W2015736195 abstract "The formation and decay kinetics of HCO(0, 0, 0) and vibrationally excited HCO were measured following the 266 nm photolysis of acetaldehyde (CH3CHO) vapor. Time-resolved intracavity laser spectroscopy was used to detect the absorption of HCO with 1–2 μs time resolution. The kinetic properties of HCO were modeled using simulations derived from measured kinetic parameters and from best-fit comparisons. The two components observed in the formation of HCO(0, 0, 0) were identified with its production by direct photolysis and by intermolecular energy transfer from vibrationally excited HCO (second-order rate coefficient k = (1.1 ± 0.3) × 10−11 molecule−1 cm3 s−1 for acetaldehyde collisions). Contributions from rotationally excited HCO were not observed." @default.
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- W2015736195 date "1986-06-01" @default.
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- W2015736195 title "Formation of vibrationally excited HCO in the photodissociation of acetaldehyde at 266 nm" @default.
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- W2015736195 doi "https://doi.org/10.1016/0301-0104(86)80073-8" @default.
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