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• W2015753606 abstract "Abstract The kinetics of oxidation of [Cr III (Dpc)(Asp)(H 2 O) 2 ] (Dpc = dipicolinic acid and Asp = DL ‐aspartic acid) by N ‐bromosuccinimide (NBS) in aqueous solution have been found to obey the equation: equation image where k 2 is the rate constant for the electron transfer process, K 1 is the equilibrium constant for deprotonation of [Cr III (Dpc)(Asp)(H 2 O) 2 ], K 2 and K 3 are the pre‐equilibrium formation constants of precursor complexes [Cr III (Dpc)(Asp)(H 2 O)(NBS)] and [Cr III (Dpc)(Asp)(H 2 O)(OH)(NBS)] − . Values of k 2 = 4.85 × 10 −2 s −1 , K 1 = 1.85 × 10 −7 mol dm −3 , and K 2 = 78.2 mol −1 dm 3 have been obtained at 30°C and I = 0.1 mol dm −3 . The experimental rate law is consistent with a mechanism in which the deprotonated [Cr III (Dpc)(Asp)(H 2 O)(OH)] − is considered to be the most reactive species compared to its conjugate acid. It is assumed that electron transfer takes place via an inner‐sphere mechanism. © 2004 Wiley Periodicals, Inc. Int J Chem Kinet 36: 394–400, 2004" @default.
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• W2015753606 date "2004-05-05" @default.
• W2015753606 modified "2023-10-13" @default.
• W2015753606 title "Kinetics and mechanism of oxidation of a ternary complex involving dipicolinatochromium(III) andDL-aspartic acid byN-bromosuccinimide" @default.
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• W2015753606 doi "https://doi.org/10.1002/kin.20014" @default.
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