FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2015763323> ?p ?o ?g. }

• W2015763323 endingPage "87" @default.
• W2015763323 startingPage "79" @default.
• W2015763323 abstract "Reaction of Si2H6 with ≥ 3 molar equivalents of CO2(CO)8 in hexane gives the closo-cluster Co4(μ4-SiCo(CO)4) (CO)11, while with < 3 molar equivalents the partially substituted cluster H2Si3Co6(CO)20 is formed. An X-ray crystal structure determination shows the latter to be relatively open, with linked SiCo2 triangles and retention of SiH bonds on two of the silicon atoms. With O(SiH3)2, Co2(CO)8 gives mainly the mono-silyl complex μ4-Si[Co2(CO)7]2, together with an unstable species tentatively identified as O{Si[Co(CO)4]Co2(CO)7}2. Reaction of S(SiH3)2 with Co2(CO) 8 gives Co4(μ4-S)2(CO)11 and the novel cluster SSi2Co2(CO)14; the latter was shown crystallographically to contain a Co2(CO)6 unit doubly-bridged by two silicon atoms that are in turn linked by the sulphur atom. There is also a terminal Co (CO)4 group attached to each silicon atom. The most notable feature of this structure is an acute SiSSi bond angle of 70.3° which leads to a very short formally non-bonded Si ⋯ Si distance of 2.498 Å." @default.
• W2015763323 created "2016-06-24" @default.
• W2015763323 creator A5013020094 @default.
• W2015763323 creator A5027195517 @default.
• W2015763323 creator A5029035624 @default.
• W2015763323 date "1993-12-01" @default.
• W2015763323 modified "2023-09-26" @default.
• W2015763323 title "Preparation and structures of mixed silicon-cobalt carbonyl clusters with SiH, SiO or SiS bonds" @default.
• W2015763323 cites W111026815 @default.
• W2015763323 cites W1561683907 @default.
• W2015763323 cites W1971490423 @default.
• W2015763323 cites W1972570681 @default.
• W2015763323 cites W1974518175 @default.
• W2015763323 cites W1974974307 @default.
• W2015763323 cites W1978059778 @default.
• W2015763323 cites W1983547841 @default.
• W2015763323 cites W1991291842 @default.
• W2015763323 cites W1991644485 @default.
• W2015763323 cites W1993640993 @default.
• W2015763323 cites W1995286436 @default.
• W2015763323 cites W1999701394 @default.
• W2015763323 cites W2001220021 @default.
• W2015763323 cites W2013632307 @default.
• W2015763323 cites W2014762490 @default.
• W2015763323 cites W2015079956 @default.
• W2015763323 cites W2015642767 @default.
• W2015763323 cites W2021395588 @default.
• W2015763323 cites W2023618226 @default.
• W2015763323 cites W2028906292 @default.
• W2015763323 cites W2033866354 @default.
• W2015763323 cites W2047607722 @default.
• W2015763323 cites W2055589611 @default.
• W2015763323 cites W2074271866 @default.
• W2015763323 cites W2075972551 @default.
• W2015763323 cites W2076958511 @default.
• W2015763323 cites W2088286113 @default.
• W2015763323 cites W2101462419 @default.
• W2015763323 cites W2115380722 @default.
• W2015763323 cites W2136971238 @default.
• W2015763323 cites W2145833418 @default.
• W2015763323 cites W2145873499 @default.
• W2015763323 cites W2149849987 @default.
• W2015763323 cites W2318022501 @default.
• W2015763323 cites W2325203204 @default.
• W2015763323 cites W2331357339 @default.
• W2015763323 cites W287218042 @default.
• W2015763323 cites W3024709322 @default.
• W2015763323 cites W4242047341 @default.
• W2015763323 doi "https://doi.org/10.1016/0022-328x(93)83343-t" @default.
• W2015763323 hasPublicationYear "1993" @default.
• W2015763323 type Work @default.
• W2015763323 sameAs 2015763323 @default.
• W2015763323 citedByCount "9" @default.
• W2015763323 countsByYear W20157633232018 @default.
• W2015763323 countsByYear W20157633232023 @default.
• W2015763323 crossrefType "journal-article" @default.
• W2015763323 hasAuthorship W2015763323A5013020094 @default.
• W2015763323 hasAuthorship W2015763323A5027195517 @default.
• W2015763323 hasAuthorship W2015763323A5029035624 @default.
• W2015763323 hasConcept C149635348 @default.
• W2015763323 hasConcept C161790260 @default.
• W2015763323 hasConcept C164866538 @default.
• W2015763323 hasConcept C178790620 @default.
• W2015763323 hasConcept C179104552 @default.
• W2015763323 hasConcept C185592680 @default.
• W2015763323 hasConcept C199360897 @default.
• W2015763323 hasConcept C2777077568 @default.
• W2015763323 hasConcept C2994067411 @default.
• W2015763323 hasConcept C41008148 @default.
• W2015763323 hasConcept C515602321 @default.
• W2015763323 hasConcept C5304478 @default.
• W2015763323 hasConcept C544956773 @default.
• W2015763323 hasConcept C58312451 @default.
• W2015763323 hasConcept C8010536 @default.
• W2015763323 hasConceptScore W2015763323C149635348 @default.
• W2015763323 hasConceptScore W2015763323C161790260 @default.
• W2015763323 hasConceptScore W2015763323C164866538 @default.
• W2015763323 hasConceptScore W2015763323C178790620 @default.
• W2015763323 hasConceptScore W2015763323C179104552 @default.
• W2015763323 hasConceptScore W2015763323C185592680 @default.
• W2015763323 hasConceptScore W2015763323C199360897 @default.
• W2015763323 hasConceptScore W2015763323C2777077568 @default.
• W2015763323 hasConceptScore W2015763323C2994067411 @default.
• W2015763323 hasConceptScore W2015763323C41008148 @default.
• W2015763323 hasConceptScore W2015763323C515602321 @default.
• W2015763323 hasConceptScore W2015763323C5304478 @default.
• W2015763323 hasConceptScore W2015763323C544956773 @default.
• W2015763323 hasConceptScore W2015763323C58312451 @default.
• W2015763323 hasConceptScore W2015763323C8010536 @default.
• W2015763323 hasIssue "1-2" @default.
• W2015763323 hasLocation W20157633231 @default.
• W2015763323 hasOpenAccess W2015763323 @default.
• W2015763323 hasPrimaryLocation W20157633231 @default.
• W2015763323 hasRelatedWork W1992523437 @default.
• W2015763323 hasRelatedWork W1994711807 @default.
• W2015763323 hasRelatedWork W2020980412 @default.
• W2015763323 hasRelatedWork W2027503670 @default.
• W2015763323 hasRelatedWork W2395178433 @default.

• next