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- W2015772652 abstract "Abstract Solid state X-ray photoelectron spectra of S 2 N 2 , S 4 N 4 , (SNBr 0.04 ) x , and (SNBr 0.25 ) x have been obtained and the gas phase spectrum of S 2 N 2 is also reported. Both the solid state and gas phase core level spectra, as well as MNDO and CHELEQ calculations, show that there is greater S → N charge transfer in S 4 N 4 than in S 2 N 2 . The solid state data indicate that the charge distributions in S 2 N 2 and (SN) x are the same. All of the data can be satisfactorily explained without recourse to N p π → S d π bonding. Bromination of an (SN) x film and single crystals results in complicated, broad N 1s and S 2p envelopes. Changes in the relative core level intensities on bromination suggest that the bromine resides largely between and/or on the (SN) x fibrils, rather than penetrating into the fibrils." @default.
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- W2015772652 date "1980-03-01" @default.
- W2015772652 modified "2023-10-12" @default.
- W2015772652 title "The application of gas phase and solid state X-ray photoelectron spectroscopy to the investigation of derivatives containing the repeating SN unit" @default.
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- W2015772652 doi "https://doi.org/10.1016/0379-6779(80)90007-7" @default.
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