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- W2015772912 abstract "A highly stereoselective Michael reduction/intramolecular Michael reaction cascade is described. The cascade is initiated by the regioselective Michael reduction of an α-methylidene ester with L-Selectride. This is followed by the highly stereoselective intramolecular Michael reaction which efficiently constructs a six-membered carbocyclic ring with formation of the trans-stereodiad, composed of an all-carbon quaternary center and a tertiary stereogenic center. The stereoselectivity is perfectly controlled by the choice of alkene geometry in the Michael acceptor." @default.
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- W2015772912 date "2014-01-01" @default.
- W2015772912 modified "2023-09-27" @default.
- W2015772912 title "Highly stereoselective Michael reduction/intramolecular Michael reaction cascade to synthesize trans-stereodiad comprising an all-carbon quaternary stereogenic center" @default.
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- W2015772912 doi "https://doi.org/10.1016/j.tetlet.2013.12.110" @default.
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