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- W2015778852 abstract "The electrochemical behavior of PdCl2(RNC)2 (1) has been investigated in acetonitrile at Pt and Hg electrodes. The cyclic voltammogram of 1 showed a reduction wave at ca. −1.2 V, corresponding to a two-electron transfer. Coulometric reduction of 1 at the Pt electrode gave a binuclear complex, Pd2Cl2(RNC)4 (2). A similar reaction at the Hg electrode gave 2 in a relatively low yield. A Pt electrode was superior to a Hg one in the electrochemical synthesis of 2. The polarogram of 1 at a Hg electrode suggested a CE mechanism of the electrode reaction." @default.
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- W2015778852 date "1987-07-01" @default.
- W2015778852 modified "2023-09-27" @default.
- W2015778852 title "Electrochemical Preparation of Tetrakis(isocyanide)dipalladium(I) Dichloride" @default.
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- W2015778852 doi "https://doi.org/10.1246/bcsj.60.2665" @default.
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