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• W2015800259 abstract "Abstract This review summarizes structural parameters for forty five Cu 4 (μ 4 -O)(η-X) 6 (L 4 ) tetramers. There are four types of structurally equal core units, CuCl 3 ON, CuCl 3 OO, CuCl 3 OCl and CuBr 3 ON. There are also tetramers which contain structurally unequal core units: CuCl 3 ON (x2) and CuCl 2 BrON (x2); CuCl 3 ON (x1), CuCl 2 BrON (x2) and CuCl 3 OCl (x1). There is a tendency for an elongated Cu⋯Cu separation as well as Cu–L bond distances with increase of the covalent radius of the coordinating atom(s). Tetrahedral distortion around oxygen atom (OCu 4 ) increases in the order: 1.67° (CuCl 3 OCl)  3 ON)  3 OO′)  3 ON). The mean Cu–Cl–Cu bridge angle of 80.5° is about 4.0° more open than that of a Cu–Br–Cu (76.5°). The cluster Cu 16 O 4 Br 7 Cl 17 (4-Mepy) 16 (4-Mepy = 4-methylpyridine) contains four crystallographically independent tetramers: Cu 4 OBrCl 5 (4-Mepy) 4 (1), Cu 4 OBrCl 5 (4-Mepy) 4 (2) Cu 4 OBr 2 Cl 4 (4-Mepy) 4 (3) and Cu 4 OBr 3 Cl 3 (4-Mepy) 4 (4), which is a unique example of stereoisomerism. There are other examples which exist in two isomeric forms. Another contains two or even four crystallographically independent tetramers within the same crystal, differing mostly by degree of distortion and is an examples of distortion isomerism. Pairs of Cu 4 OCl 6 ( n -Meim) 4 ( n -Meim =  n -methylimidazole) ( n  = 1 or 2) are examples of ligand isomerism." @default.
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• W2015800259 date "2011-08-01" @default.
• W2015800259 modified "2023-10-08" @default.
• W2015800259 title "Tetramers Cu4(μ4-O)(η-X)6(L4): Analysis of structural data" @default.
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• W2015800259 doi "https://doi.org/10.1016/j.ccr.2010.12.005" @default.
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