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- W2015817059 abstract "An efficient highly enantioselective (ee ≥99%) synthesis of α-ionone and α-damascone is described. Both enantiomers of title compounds were synthesized through two straightforward pathways diverging from enantiopure (R)- or (S)-α-cyclogeraniol. These versatile building blocks were obtained by regioselective ZrCl4-promoted biomimetic cyclization of (6S)- or (6R)-(Z)-6,7-epoxygeraniol, respectively, followed by deoxygenation of the so formed secondary alcohol. The chiral information was encoded by a highly regioselecive Sharpless asymmetric dihydroxylation of inexpensive geranyl acetate." @default.
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- W2015817059 date "2004-11-11" @default.
- W2015817059 modified "2023-10-17" @default.
- W2015817059 title "A Simple and Efficient Highly Enantioselective Synthesis of α-Ionone and α-Damascone" @default.
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- W2015817059 doi "https://doi.org/10.1021/jo049012j" @default.
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