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• W2015845108 abstract "The title compounds 4 and 12 are prepared by reacting bis{(η2-ethene)}(η5-pentamethylcyclopentadienyl)cobalt(I) 3 with Weidenbruch’s stannylene bis[bis{6-tert-butyl-2,3,4-trimethylphenyl}tin] (1) employing different thermal reaction conditions. Compounds 4 and 12 are rare examples of transition metal complexes of 1. According to an X-ray crystal structure determination, 4 displays a half-sandwich structure with trigonal planar coordinated Co atom and a subvalent Sn(II) center. The Co–Sn bond length in 4 is 2.3926(4) Å and represents one of the shortest reported so far. A comparison of relevant bonding parameters of 4 and several related Co–Sn half-sandwich compounds containing low valent SnR2 fragments reveals comparable steric and electronic effects of the stannylenes towards the 16 e {(η2-ethene)(Me5C5)Co} fragment in these complexes. In contrast to the isostructural ethene/stannylene complex bis{methyl(trimethylsilyl)}stannio(η2-ethene)(η5-cyclopentadienyl)cobalt 6 containing Lappert’s bis(stannanediyl) 2, 4 is inert towards H2O and does not activate water by an oxidative addition reaction to give a mixed hydroxo hydrido complex. At elevated temperatures, 4 reacts via ethene dissociation and ligand redistribution to form the trinuclear cobalt bis stannylene half sandwich complex Bis[bis{6-tert-butyl-2,3,4-trimethylphenyl}]stannio(η5-pentamethylcyclopentadienyl)}cobalt(I) 12 in moderate yields." @default.
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• W2015845108 date "1999-07-01" @default.
• W2015845108 modified "2023-10-18" @default.
• W2015845108 title "Synthesis and structure of dinuclear [(2-tert-butyl-4,5,6-trimethylphenyl)2Sn-Co(η2-ethene)(η5-Me5C5)] and its thermal conversion to trinuclear [{(2-tert-butyl-4,5,6-trimethylphenyl)2Sn}2Co(η5-Me5C5)] (Co–Sn2)" @default.
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• W2015845108 doi "https://doi.org/10.1016/s0022-328x(99)00172-2" @default.
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