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- W2015854304 abstract "Electrochemical oxidation of [V(IV)O(nta)(H 2 O)] - (H 3 nta nitrilotriacetic acid) was studied in aqueous solution by means of cyclic voltammetry, differential pulse polarography, and current sampled DC polarography on mercury as electrode material. In the pH-range under study (5.5-9.0) the corresponding V(V) complex is produced by one-electron oxidation of the parent V(IV) species. The oxidation product is stable within the time scale of cyclic voltammetry. The evaluation of the pH-dependence of the half-wave potentials leads to a p K a value for [V(IV)O(nta)(H 2 O)] - which is in a good agreement with previous determinations. The measured value for E 1/2 is very close to the formal potential E 0 calculated via the Nernst equation on the basis of known literature values for log K ox and log K red , the complex stability constants for the oxidized and reduced form, respectively." @default.
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- W2015854304 date "1989-01-01" @default.
- W2015854304 modified "2023-09-23" @default.
- W2015854304 title "Electroanalytical chemistry of vanadium complexes: Electrochemical oxidation of [V(IV)O(nta)(H2O)]-" @default.
- W2015854304 doi "https://doi.org/10.1135/cccc19890064" @default.
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