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- W2015855952 abstract "Extraction behavior of neptunium (Np) by tri-n-butyl phosphate from calcium nitrate hydrate melt was investigated. Distribution ratio of Np was found to increase with the decrease of water content. Adding nitric acid into the system resulted in an increase of the distribution ratio. In order to understand the extraction trends, Np species in the hydrate melt were analyzed by Raman spectrometry and UV/Vis/NIR spectrometry. Major fraction was assigned to be NpO22+ of Np(VI) and small fraction to be NpO2+ of Np(V). A shift of the v1 symmetric vibrational frequency of NpO22+ in nitrate media was found in Raman spectra. This suggests a coordination circumstance change of NpO22+." @default.
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- W2015855952 date "2010-03-01" @default.
- W2015855952 modified "2023-09-27" @default.
- W2015855952 title "Study on coordination characteristics of neptunium and uranium ions in calcium nitrate hydrate melt by Raman spectrometry and UV/Vis/NIR spectrometry" @default.
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- W2015855952 doi "https://doi.org/10.1088/1757-899x/9/1/012061" @default.
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