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- W2015870777 abstract "Abstract The switchable/tunable electrocatalysis is of great importance in both fundamental and application research. In this work, we synthesize the CS−Fe(notpH 3 ) hybrids film by the simple one-step electrodeposition technique (CS: chitosan; Fe(notpH 3 ): 1,4,7-triazacyclononane-1,4,7-triyl-tris methylene-phosphonic acid iron(III) complex). The stable immobilization of Fe(notpH 3 ) in CS polymer originates from the strong electrostatic and/or hydrogen bonding interactions between Fe(notpH 3 ) and CS, which also enhances the insolubility of CS in acidic solution. The immobilized Fe(notpH 3 ) complex undergoes an effective direct electron transfer reaction and shows a particular pH-sensitive electrochemical property. Based on the particular formal potential hopping mechanism of Fe(notpH 3 ) complex, the CS–Fe(notpH 3 ) hybrids film can be further used to realize pH-controlled switchable electrocatalysis toward H 2 O 2 reduction." @default.
- W2015870777 created "2016-06-24" @default.
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- W2015870777 date "2014-03-01" @default.
- W2015870777 modified "2023-09-23" @default.
- W2015870777 title "One-step electrodeposition of chitosan/phosphonate iron(III) hybrids film and its pH-controlled switchable electrocatalytic behavior" @default.
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- W2015870777 doi "https://doi.org/10.1016/j.jelechem.2014.01.003" @default.
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