Matches in SemOpenAlex for { <https://semopenalex.org/work/W2015875114> ?p ?o ?g. }
- W2015875114 endingPage "2421" @default.
- W2015875114 startingPage "2409" @default.
- W2015875114 abstract "Compared are recent EPR, susceptibility, and neutron measurements of both $S$-state (${b}_{4}^{0}$) and non-$S$-state (${A}_{4}^{0}〈{r}^{4}〉$) lanthanide-ion crystal-field splittings in metals. The ratio of the $S$-state to the non-$S$-state fields $mathcal{R}=frac{{b}_{4}^{0}}{{A}_{4}^{0}〈{r}^{4}〉}$ in some metals is anomalously large and cannot be explained by the current insulator theory. We suggest that there must exist an extra metallic contribution to both ${A}_{4}^{0}〈{r}^{4}〉$ and the ratio $mathcal{R}$. The non-$S$-state field ${A}_{4}^{0}〈{r}^{4}〉$ is divided into two: (i) all Coulombic and exchange contributions, and (ii) a covalent contribution similar to that found in insulators. We show that the latter term is more efficient in its contribution to the $S$-state field ${b}_{4}^{0}$. We suggest, in the anomalous metals, the $S$ state ${b}_{4}^{0}$ is dominated by covalent mixing but that for the non-$S$-state ions there is a partial cancellation between covalent and the coulomb-field contributions. Finally the implications for the ${mathrm{Gd}}^{3+}$, $4{f}^{7}$ to $4{f}^{8}$ interconfigurational energy are explained." @default.
- W2015875114 created "2016-06-24" @default.
- W2015875114 creator A5007389249 @default.
- W2015875114 creator A5027527616 @default.
- W2015875114 creator A5072383746 @default.
- W2015875114 date "1978-09-15" @default.
- W2015875114 modified "2023-09-25" @default.
- W2015875114 title "Anomalous crystal-field splittings of lanthanideS-states in metals" @default.
- W2015875114 cites W1640361596 @default.
- W2015875114 cites W1644398806 @default.
- W2015875114 cites W1967548910 @default.
- W2015875114 cites W1971472669 @default.
- W2015875114 cites W1973839941 @default.
- W2015875114 cites W1979646510 @default.
- W2015875114 cites W1979712899 @default.
- W2015875114 cites W1983090386 @default.
- W2015875114 cites W1989208425 @default.
- W2015875114 cites W1990453052 @default.
- W2015875114 cites W1996242361 @default.
- W2015875114 cites W2003692296 @default.
- W2015875114 cites W2013438177 @default.
- W2015875114 cites W2013964668 @default.
- W2015875114 cites W2016309498 @default.
- W2015875114 cites W2018118970 @default.
- W2015875114 cites W2026198698 @default.
- W2015875114 cites W2027022015 @default.
- W2015875114 cites W2027756926 @default.
- W2015875114 cites W2030515810 @default.
- W2015875114 cites W2041492421 @default.
- W2015875114 cites W2048157199 @default.
- W2015875114 cites W2049891421 @default.
- W2015875114 cites W2050806231 @default.
- W2015875114 cites W2053244914 @default.
- W2015875114 cites W2057120994 @default.
- W2015875114 cites W2060233426 @default.
- W2015875114 cites W2061144280 @default.
- W2015875114 cites W2064227336 @default.
- W2015875114 cites W2065686520 @default.
- W2015875114 cites W2067057692 @default.
- W2015875114 cites W2075597369 @default.
- W2015875114 cites W2079444003 @default.
- W2015875114 cites W2080143275 @default.
- W2015875114 cites W2087975371 @default.
- W2015875114 cites W2089082476 @default.
- W2015875114 cites W2089989929 @default.
- W2015875114 cites W2090638408 @default.
- W2015875114 cites W2093972725 @default.
- W2015875114 cites W2115715809 @default.
- W2015875114 cites W2135175103 @default.
- W2015875114 doi "https://doi.org/10.1103/physrevb.18.2409" @default.
- W2015875114 hasPublicationYear "1978" @default.
- W2015875114 type Work @default.
- W2015875114 sameAs 2015875114 @default.
- W2015875114 citedByCount "40" @default.
- W2015875114 countsByYear W20158751142016 @default.
- W2015875114 countsByYear W20158751142018 @default.
- W2015875114 crossrefType "journal-article" @default.
- W2015875114 hasAuthorship W2015875114A5007389249 @default.
- W2015875114 hasAuthorship W2015875114A5027527616 @default.
- W2015875114 hasAuthorship W2015875114A5072383746 @default.
- W2015875114 hasConcept C11413529 @default.
- W2015875114 hasConcept C121332964 @default.
- W2015875114 hasConcept C122290 @default.
- W2015875114 hasConcept C145148216 @default.
- W2015875114 hasConcept C147120987 @default.
- W2015875114 hasConcept C180577832 @default.
- W2015875114 hasConcept C184779094 @default.
- W2015875114 hasConcept C185544564 @default.
- W2015875114 hasConcept C191897082 @default.
- W2015875114 hasConcept C192562407 @default.
- W2015875114 hasConcept C201770740 @default.
- W2015875114 hasConcept C202444582 @default.
- W2015875114 hasConcept C26873012 @default.
- W2015875114 hasConcept C33923547 @default.
- W2015875114 hasConcept C41008148 @default.
- W2015875114 hasConcept C48103436 @default.
- W2015875114 hasConcept C544153396 @default.
- W2015875114 hasConcept C62520636 @default.
- W2015875114 hasConcept C9342510 @default.
- W2015875114 hasConcept C9652623 @default.
- W2015875114 hasConceptScore W2015875114C11413529 @default.
- W2015875114 hasConceptScore W2015875114C121332964 @default.
- W2015875114 hasConceptScore W2015875114C122290 @default.
- W2015875114 hasConceptScore W2015875114C145148216 @default.
- W2015875114 hasConceptScore W2015875114C147120987 @default.
- W2015875114 hasConceptScore W2015875114C180577832 @default.
- W2015875114 hasConceptScore W2015875114C184779094 @default.
- W2015875114 hasConceptScore W2015875114C185544564 @default.
- W2015875114 hasConceptScore W2015875114C191897082 @default.
- W2015875114 hasConceptScore W2015875114C192562407 @default.
- W2015875114 hasConceptScore W2015875114C201770740 @default.
- W2015875114 hasConceptScore W2015875114C202444582 @default.
- W2015875114 hasConceptScore W2015875114C26873012 @default.
- W2015875114 hasConceptScore W2015875114C33923547 @default.
- W2015875114 hasConceptScore W2015875114C41008148 @default.
- W2015875114 hasConceptScore W2015875114C48103436 @default.
- W2015875114 hasConceptScore W2015875114C544153396 @default.
- W2015875114 hasConceptScore W2015875114C62520636 @default.