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• W2015877441 abstract "A series of new functional amino acids were prepared in high yield via thiol–ene Michael addition between l-cysteine and monomethoxy oligo(ethylene glycol) (OEG) functionalized methacrylates (OEGxMA) and acrylate (OEGxA). These OEGylated cysteine derivatives were converted into polymerizable N-carboxyanhydride (NCA) monomers using triphosgene. Subsequent ring-opening polymerization (ROP) of these NCA monomers gave a series of OEGylated poly-l-cysteine (poly-EGxMA-C or poly-EGxA-C) homopolypeptides. Depending on the length of OEG side chains, poly-EGxMA-C and poly-EGxA-C polypeptides displayed different solubility and secondary structure in water. More importantly, the obtained polypeptides can display reversible thermoresponsive properties in water when the x value is between 3 and 5. The synthetic strategy represents a highly efficient method to prepare nonionic functional polypeptides with tunable thermoresponsive properties." @default.
• W2015877441 created "2016-06-24" @default.
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• W2015877441 date "2013-04-30" @default.
• W2015877441 modified "2023-10-14" @default.
• W2015877441 title "Thermoresponsive Oligo(ethylene glycol) Functionalized Poly-<scp>l</scp>-cysteine" @default.
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• W2015877441 doi "https://doi.org/10.1021/ma400678w" @default.
• W2015877441 hasPublicationYear "2013" @default.
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