Matches in SemOpenAlex for { <https://semopenalex.org/work/W2015901181> ?p ?o ?g. }
Showing items 1 to 66 of
66
with 100 items per page.
- W2015901181 endingPage "1294" @default.
- W2015901181 startingPage "1290" @default.
- W2015901181 abstract "Mercarbide [CHg4O2](OH)2, is a mercury derivative of ethane in which all of the ethane hydrogen atoms are substituted by mercury atoms. Mercarbide exhibits basic and anion exchange properties in addition to showing unique stability towards mineral acids as well as oxidizing and reducing agents. The selectivity of mercarbide towards organic anions shows selectivity dependence on the size and configuration of the pendant hydrocarbon group. Titration of mercarbide with Hammett indicators shows that mercarbide in its hydroxide form is a solid base with sites allocation 7.2 < H0 < 26.5. Studies of the catalytic activity of mercarbide towards alcohol oxyethylation and aldol condensation show that it functions as a homogeneous basic catalyst, but with increased activity owing to the higher basicity of its active sites. The present paper reviews the synthesis, structure, physicochemical, and catalytic properties of mercarbide." @default.
- W2015901181 created "2016-06-24" @default.
- W2015901181 creator A5028819474 @default.
- W2015901181 date "2010-06-01" @default.
- W2015901181 modified "2023-09-23" @default.
- W2015901181 title "Mercarbide: An unusual organomercury polymer" @default.
- W2015901181 cites W1976920095 @default.
- W2015901181 cites W2006926835 @default.
- W2015901181 cites W2012604569 @default.
- W2015901181 cites W2031130045 @default.
- W2015901181 cites W2059838247 @default.
- W2015901181 cites W2157445280 @default.
- W2015901181 cites W2399728278 @default.
- W2015901181 cites W422586882 @default.
- W2015901181 cites W619253825 @default.
- W2015901181 doi "https://doi.org/10.1016/j.ccr.2009.12.014" @default.
- W2015901181 hasPublicationYear "2010" @default.
- W2015901181 type Work @default.
- W2015901181 sameAs 2015901181 @default.
- W2015901181 citedByCount "1" @default.
- W2015901181 countsByYear W20159011812014 @default.
- W2015901181 crossrefType "journal-article" @default.
- W2015901181 hasAuthorship W2015901181A5028819474 @default.
- W2015901181 hasConcept C118792377 @default.
- W2015901181 hasConcept C161790260 @default.
- W2015901181 hasConcept C178790620 @default.
- W2015901181 hasConcept C179104552 @default.
- W2015901181 hasConcept C184866935 @default.
- W2015901181 hasConcept C185592680 @default.
- W2015901181 hasConcept C18616679 @default.
- W2015901181 hasConcept C188027245 @default.
- W2015901181 hasConcept C2775896084 @default.
- W2015901181 hasConcept C2777207669 @default.
- W2015901181 hasConcept C77176794 @default.
- W2015901181 hasConceptScore W2015901181C118792377 @default.
- W2015901181 hasConceptScore W2015901181C161790260 @default.
- W2015901181 hasConceptScore W2015901181C178790620 @default.
- W2015901181 hasConceptScore W2015901181C179104552 @default.
- W2015901181 hasConceptScore W2015901181C184866935 @default.
- W2015901181 hasConceptScore W2015901181C185592680 @default.
- W2015901181 hasConceptScore W2015901181C18616679 @default.
- W2015901181 hasConceptScore W2015901181C188027245 @default.
- W2015901181 hasConceptScore W2015901181C2775896084 @default.
- W2015901181 hasConceptScore W2015901181C2777207669 @default.
- W2015901181 hasConceptScore W2015901181C77176794 @default.
- W2015901181 hasIssue "11-12" @default.
- W2015901181 hasLocation W20159011811 @default.
- W2015901181 hasOpenAccess W2015901181 @default.
- W2015901181 hasPrimaryLocation W20159011811 @default.
- W2015901181 hasRelatedWork W1964133851 @default.
- W2015901181 hasRelatedWork W1976860724 @default.
- W2015901181 hasRelatedWork W1984039808 @default.
- W2015901181 hasRelatedWork W2001889746 @default.
- W2015901181 hasRelatedWork W2017331403 @default.
- W2015901181 hasRelatedWork W2054312027 @default.
- W2015901181 hasRelatedWork W2057808024 @default.
- W2015901181 hasRelatedWork W2144794950 @default.
- W2015901181 hasRelatedWork W2800969195 @default.
- W2015901181 hasRelatedWork W3034891300 @default.
- W2015901181 hasVolume "254" @default.
- W2015901181 isParatext "false" @default.
- W2015901181 isRetracted "false" @default.
- W2015901181 magId "2015901181" @default.
- W2015901181 workType "article" @default.