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- W2015954743 abstract "Reaction of the sodium salt NaC5H4Y (Y CH2C5H5) which is obtained from CH2(C5H5)2 and NaNH2 in THF with halogeno metal compounds [M(Hal)Lm]n gives the complexes (C5H4Y)ML2 (1–8) in good yields. The 13C and 31P NMR spectra of these mononuclear compounds show that the substituent Y is linked to the π-bonded ring in two isomeric forms. Metalation of (C5H4Y)Rh(PhCCPh)(P-i-Pr3) (2) and (C5H4Y)Ir(C8H14)2 (4) with n-BuLi in ether affords the lithiated derivatives (LiC5H4CH2C5H4)ML2 (9, 10) which react with [Rh(CO)2Cl]2 and [CoI(CO)4] to give the heterodinuclear complexes 12–14. A second route to compounds generally formulated as (L2M)(C5H4CH2C5H4)(M′L′2) which avoids the preparation of lithiated intermediates and uses trans-[Rh(CCMe)(py)(P-i-Pr3)2] (15) as a substrate is also described." @default.
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- W2015954743 date "1990-02-01" @default.
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- W2015954743 title "Bis(cyclopentadienyl)methan-verbrückte zweikernkomplexe III. Ein neuer weg zu heteronuclearen zweikernkomplexen mit [CH2(C5H4)2]2− als Brückenliganden" @default.
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- W2015954743 doi "https://doi.org/10.1016/0022-328x(90)87080-w" @default.
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