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- W2015977811 abstract "Abstract To describe aromaticity of planar and three‐dimensional molecules, different electron counting rules are employed. Here, the relationship between the Hückel 4 n + 2 rule and the Hirsch 2( n + 1) 2 rule is established based on formal approach considering the electrons as objects in an arbitrary n ‐dimensional space of states . Two types of three‐dimensional aromaticity, referred to as ‘spherical’ (following the 4 n + 2 electron counting rule) and ‘spatial’ (following the 2( n + 1) 2 electron counting rule) are distinguished. A conclusion concerning the boundaries of the Periodic Table of Elements is made based on the same formal approach that no g ‐ (or higher) elements can exist and that possible extension of the Periodic Table beyond the seventh period must be followed by filling of the 8p or inner 6f or 7d levels. Copyright © 2011 John Wiley & Sons, Ltd." @default.
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- W2015977811 date "2011-01-12" @default.
- W2015977811 modified "2023-10-18" @default.
- W2015977811 title "Electron-counting rules, three-dimensional aromaticity, and the boundaries of the Periodic Table" @default.
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- W2015977811 doi "https://doi.org/10.1002/poc.1830" @default.
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