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- W2015979157 abstract "Abstract The kinetics of the catalytic effect of Mo2O4(H2O)2+6 on the iodide oxidation by chlorate was studied at different temperatures (25–45°C) in Ar-saturated acid aqueous solutions under conditions of excess iodide ion by monitoring the formation of I−3 at 352 nm. The initial reaction rate at 30°C is represented by the following equation: v = 1 3 d[I−3]/d t = kMo[H+]2[I−][ClO−3] with kMo = 9 × 10−5 s−1 · M−3 + 0.73 s−1 · M−3 [H+]−1[Mo2O2+4] where the brackets indicate molar concentrations and time is expressed in seconds. A mechanism, which includes the formation of a dimeric molybdenum complex as rate determining step, is proposed to account for the experimental results." @default.
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- W2015979157 date "1997-08-01" @default.
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- W2015979157 title "The catalytic effect of MoV on the oxidation of iodide by chlorate" @default.
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- W2015979157 doi "https://doi.org/10.1016/s1381-1169(97)00060-5" @default.
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