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- W2015981909 abstract "Magnesium chloride crystals homogeneously doped with titanium ions can be prepared by crystal growth from the melt. The electronic spectrum taken along the c-axis indicates that the titanium ions are six coordinate and divalent. The x band electron spin resonance consists of a series of sharp lines and the nuclear hyperfine due to 47Ti and 49Ti can be observed. The peaks are assigned to a forbidden Ms = 2 double quantum transition and orientation studies indicate that the environment is trigonally distorted. These measurements make it possible to interpret the powder spectrum. The powder along with an aluminium alkyl is a catalyst for the polymerization of ethene and a comparison is made between the powder ESR and ESR signals observed in the polymerization of ethene using a conventional Ziegler-Natta catalyst of titanium tetrachloride, magnesium chloride and aluminium triethyl." @default.
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- W2015981909 date "1985-08-01" @default.
- W2015981909 modified "2023-09-27" @default.
- W2015981909 title "Electron spin resonance of divalent titanium ions doped into a magnesium chloride host lattice" @default.
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- W2015981909 doi "https://doi.org/10.1016/s0020-1693(00)86752-3" @default.
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