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- W2015986987 abstract "Diffusion properties of Li ion in a cathode material of amorphous LixV2O5 with 5 mol% P2O5 (x=0.2−2) were studied by means of 7Li NMR. From the relaxation time, T1ϱ, the diffusion coefficient at 25°C was obtained to be 4×10−14cm2s−1 for x=0.2 and 2.8×10−12cm2s−1 for x=2. Both pre-exponential factor, D0, and the activation energy, Ea, of the diffusion coefficient decreased with the increase of x. From the second moment, Li+ ions seemed to occupy sites approximately 2.9 A apart in a large cavity similar to that in the crystalline V2O5. It was suggested that there are three kinds of sites for the Li+ ion in the cavity, and that the ion changes the site of one kind to the others at x⋍0.6." @default.
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- W2015986987 date "1989-01-01" @default.
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- W2015986987 title "NMR study on the Li diffusion in a cathode material of amorphous vanadium pentoxide-5 mol% phosphorus pentoxide" @default.
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- W2015986987 doi "https://doi.org/10.1016/0025-5408(89)90011-1" @default.
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