Matches in SemOpenAlex for { <https://semopenalex.org/work/W2015989450> ?p ?o ?g. }
- W2015989450 endingPage "1208" @default.
- W2015989450 startingPage "1203" @default.
- W2015989450 abstract "Bimetallic Pd−Au and Pt−Au and monometallic Pd, Pt, and Au films were prepared by physical vapor deposition. The resulting surfaces were characterized by means of XPS, AFM, and CO adsorption from the liquid phase (CH2Cl2) monitored by ATR-IR spectroscopy. CO adsorption combined with ATR-IR proved to be a very sensitive method for probing the degree of interdiffusion occurring at the interfaces whose properties were altered by variation of the Pd and Pt film thickness from 0.2 to 2 nm. Because no CO adsorption was observed on Au, the evaporation of Pt-group metals on Au allowed us to study the effect of dilution on the adsorption properties of the surfaces. At equivalent Pd film thickness, the evaporation of Au reduced the amount of adsorbed CO and caused the formation of 2-fold bridging CO, which was almost absent in monometallic surfaces. Additionally, the average particle size on Pd−Au surfaces was smaller than that on monometallic Pd surfaces. The results indicate that a Pd/Au diffuse interface is formed that affects the Pd particle size even more drastically than the simple decrease in Pd film thickness in monometallic surfaces. Pt−Au surfaces were less sensitive to CO adsorption, indicating that the two metals do not mix to a significant extent. The difference in the interfacial behavior of Pd and Pt in the bimetallic gold films is traced to the largely different Pd−Au and Pt−Au miscibility gaps." @default.
- W2015989450 created "2016-06-24" @default.
- W2015989450 creator A5015517810 @default.
- W2015989450 creator A5040833016 @default.
- W2015989450 creator A5041281246 @default.
- W2015989450 creator A5041651435 @default.
- W2015989450 creator A5060789054 @default.
- W2015989450 creator A5078718425 @default.
- W2015989450 date "2006-12-09" @default.
- W2015989450 modified "2023-10-17" @default.
- W2015989450 title "Probing the Interface in Vapor-Deposited Bimetallic Pd−Au and Pt−Au Films by CO Adsorption from the Liquid Phase" @default.
- W2015989450 cites W1610059667 @default.
- W2015989450 cites W161647483 @default.
- W2015989450 cites W1964024584 @default.
- W2015989450 cites W1970652031 @default.
- W2015989450 cites W1977630559 @default.
- W2015989450 cites W1989219711 @default.
- W2015989450 cites W1990439537 @default.
- W2015989450 cites W2000803612 @default.
- W2015989450 cites W2001059915 @default.
- W2015989450 cites W2002128102 @default.
- W2015989450 cites W2002706211 @default.
- W2015989450 cites W2004900741 @default.
- W2015989450 cites W2005839737 @default.
- W2015989450 cites W2008923294 @default.
- W2015989450 cites W2010154632 @default.
- W2015989450 cites W2011074542 @default.
- W2015989450 cites W2014528698 @default.
- W2015989450 cites W2018764019 @default.
- W2015989450 cites W2023524562 @default.
- W2015989450 cites W2026912424 @default.
- W2015989450 cites W2028125671 @default.
- W2015989450 cites W2028508381 @default.
- W2015989450 cites W2030288728 @default.
- W2015989450 cites W2033412312 @default.
- W2015989450 cites W2035826213 @default.
- W2015989450 cites W2042003689 @default.
- W2015989450 cites W2047708749 @default.
- W2015989450 cites W2048210019 @default.
- W2015989450 cites W2049401837 @default.
- W2015989450 cites W2052395924 @default.
- W2015989450 cites W2054459835 @default.
- W2015989450 cites W2066978126 @default.
- W2015989450 cites W2068639376 @default.
- W2015989450 cites W2070896435 @default.
- W2015989450 cites W2073203435 @default.
- W2015989450 cites W2075140838 @default.
- W2015989450 cites W2081374501 @default.
- W2015989450 cites W2083369802 @default.
- W2015989450 cites W2083482832 @default.
- W2015989450 cites W2086631167 @default.
- W2015989450 cites W2088496023 @default.
- W2015989450 cites W2090173166 @default.
- W2015989450 cites W2091214840 @default.
- W2015989450 cites W2091261872 @default.
- W2015989450 cites W2099881142 @default.
- W2015989450 cites W2139645625 @default.
- W2015989450 cites W2145413612 @default.
- W2015989450 cites W2623299482 @default.
- W2015989450 cites W4245731997 @default.
- W2015989450 doi "https://doi.org/10.1021/la0623477" @default.
- W2015989450 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17241033" @default.
- W2015989450 hasPublicationYear "2006" @default.
- W2015989450 type Work @default.
- W2015989450 sameAs 2015989450 @default.
- W2015989450 citedByCount "10" @default.
- W2015989450 countsByYear W20159894502012 @default.
- W2015989450 countsByYear W20159894502013 @default.
- W2015989450 countsByYear W20159894502021 @default.
- W2015989450 crossrefType "journal-article" @default.
- W2015989450 hasAuthorship W2015989450A5015517810 @default.
- W2015989450 hasAuthorship W2015989450A5040833016 @default.
- W2015989450 hasAuthorship W2015989450A5041281246 @default.
- W2015989450 hasAuthorship W2015989450A5041651435 @default.
- W2015989450 hasAuthorship W2015989450A5060789054 @default.
- W2015989450 hasAuthorship W2015989450A5078718425 @default.
- W2015989450 hasConcept C113196181 @default.
- W2015989450 hasConcept C121332964 @default.
- W2015989450 hasConcept C127413603 @default.
- W2015989450 hasConcept C147789679 @default.
- W2015989450 hasConcept C150394285 @default.
- W2015989450 hasConcept C161790260 @default.
- W2015989450 hasConcept C175708663 @default.
- W2015989450 hasConcept C178790620 @default.
- W2015989450 hasConcept C185592680 @default.
- W2015989450 hasConcept C187530423 @default.
- W2015989450 hasConcept C191897082 @default.
- W2015989450 hasConcept C192562407 @default.
- W2015989450 hasConcept C42360764 @default.
- W2015989450 hasConcept C43411465 @default.
- W2015989450 hasConcept C44280652 @default.
- W2015989450 hasConcept C502130503 @default.
- W2015989450 hasConcept C518104683 @default.
- W2015989450 hasConcept C544153396 @default.
- W2015989450 hasConcept C61441594 @default.
- W2015989450 hasConcept C97355855 @default.
- W2015989450 hasConceptScore W2015989450C113196181 @default.
- W2015989450 hasConceptScore W2015989450C121332964 @default.