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- W2016011094 abstract "Starting from a 1,1′-bis-(SC)-(methoxymethyl)pyrrolidine functionalized ferrocene, an ortholithiation/iodination/chiral auxiliary removal/Suzuki coupling sequence has been achieved. It affords a convenient, stereoselective access to chiral, C2-symmetric, tetrasubstituted ferrocene derivatives of (Spl,Spl)-configuration, bearing various aryl substituents and acetoxymethyl functions. These α-acetoxy-functionalized ferrocenes may be useful synthetic intermediates. In this work they were used as precursors for two new enantiomerically pure (Spl,Spl)-2-phospha[3]ferrocenophanes for organocatalytic purposes." @default.
- W2016011094 created "2016-06-24" @default.
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- W2016011094 date "2012-10-01" @default.
- W2016011094 modified "2023-10-06" @default.
- W2016011094 title "Stereoselective synthesis of planar chiral 2,2′-diarylsubstituted ferrocene derivatives as precursors for new 2-phospha[3]ferrocenophanes" @default.
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- W2016011094 doi "https://doi.org/10.1016/j.jorganchem.2012.06.033" @default.
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