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- W2016016681 abstract "Abstract Dielectric studies on copper doped derivatives of polycrystalline layered mixed alkali trititanate Na 1.8 K 0.2 Ti 3 O 7 ceramics indicate that the losses are of mixed type and decrease on copper doping. However, the temperature dependent permittivity plots are characteristic of the diffuse nature of a possible ferroelectric phase transition and hence give indication of relaxor ferroelectric behaviour. From the EPR spectra, recorded at room temperature, it can be seen that the substitution of copper occurs at Ti 4+ as preferred site with a divalent oxidation state (Cu 2+ ) for all compositions. Also, copper doping enhances the transition temperature, which is indicative of the stabilization of the existing ferroelectric phase up higher temperatures. Besides bolstering electron hopping conduction, acceptor doping restrains the interlayer ionic conduction. Moreover, electron hopping (polaron) conduction is dominant over the lower temperature region, while interlayer ionic conduction prevails in the higher temperature region." @default.
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- W2016016681 date "2006-08-01" @default.
- W2016016681 modified "2023-09-27" @default.
- W2016016681 title "Dielectric-spectroscopic and a.c. conductivity investigations on copper doped layered Na1.8K0.2Ti3O7 ceramics" @default.
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- W2016016681 doi "https://doi.org/10.1016/j.ssc.2006.06.009" @default.
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