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- W2016018733 abstract "Acetonitrile may be used as a chemical ionization reagent gas in ion-trap mass spectrometry for the location of double bonds in functionalized long-chain monoenes. [C3H4N]+, derived from acetonitrile, reacts with carbon–carbon double bonds, generating one or a pair of fragment ions characteristic of the position of the double bond in the chain. Tolerance of a range of functional groups is achieved by isolating [C3H4N]+ from the other acetonitrile ions before reaction with the alkene. Under these conditions, competing processes such as protonation are minimized, and a different mode of fragmentation from that previously observed with unfunctionalized alkenes11 is obtained. The technique is highly sensitive (<0.5 ng), allowing its use in the identification of insect pheromones. Copyright © 1999 John Wiley & Sons, Ltd." @default.
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- W2016018733 date "1999-03-15" @default.
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- W2016018733 title "Determination of the double bond position in functionalized monoenes by chemical ionization ion-trap mass spectrometry using acetonitrile as a reagent gas" @default.
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- W2016018733 doi "https://doi.org/10.1002/(sici)1097-0231(19990315)13:5<331::aid-rcm487>3.0.co;2-a" @default.
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