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• W2016027817 abstract "Abstract Well‐defined poly( m ‐phenylene) (PMP), which is poly(1,3‐dibutoxy‐ m ‐phenylene), was successfully synthesized via Grignard metathesis polymerization. PMP with a reasonably high number‐average molecular weight ( M n ) of 25,900 and a very low polydispersity index of 1.07 was obtained. The polymerization of a Grignard reagent monomer, 1‐bromo‐2,4‐dibutoxy‐5‐chloromagnesiobenzene, proceeded in a chain‐growth manner, probably due to the meta‐substituted design producing a short distance between the MgCl and Br groups and thereby making a smooth nickel species (CNiC) transfer to the intramolecular chain end (CNiBr) over a benzene ring. PMP showed a good solubility in the common organic solvents, such as tetrahydrofuran, CH 2 Cl 2 , and CHCl 3 . Furthermore, a new block copolymer comprised of PMP and poly(3‐hexylthiophene) was also prepared. The tapping mode atomic force microscopy image of the surface of the block copolymer thin film on a mica substrate showed a nanofibril morphology with a clear contrast. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011." @default.
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• W2016027817 date "2011-04-27" @default.
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• W2016027817 title "Synthesis of poly(<i>m</i> -phenylene) and poly(<i>m</i> -phenylene)-<i>block</i> - poly(3-hexylthiophene) with low polydispersities" @default.
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• W2016027817 doi "https://doi.org/10.1002/pola.24703" @default.
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