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- W2016029217 abstract "Ultraviolet (UV) transparency and local structural environment of fluorophosphate glasses in the Ba(PO3)2–MgF2–CaF2–AlF3 system have been studied with increasing fluoride content (covering the whole compositional range) by infrared (IR) reflection spectroscopy (IRRS) in conjunction with 31P magic angle spinning (MAS) nuclear magnetic resonance (NMR) spectroscopy. UV cutoff of the glasses shifts towards longer wavelength with increasing fluoride up to ∼36 mol%. IRRS spectra indicate a gradual increase in nonbridging oxygens (NBOs) in this region. According to 31P MAS NMR spectra, it is due to the combined effects of gradual increase in Q1 sites and P–O–Al bridges (increase in optical basicity). Beyond ∼36 mol% fluoride content, the UV cutoff shifts towards shorter wavelength. It is attributed to decrease in NBOs or Q1 sites (decrease in optical basicity) as revealed in the IRRS and 31P MAS NMR spectra, respectively. In this region, true partial role of the metal fluorides in controlling UV transparency has been found to contribute significantly as well." @default.
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- W2016029217 date "2002-12-01" @default.
- W2016029217 modified "2023-10-16" @default.
- W2016029217 title "UV transparency and structure of fluorophosphate glasses" @default.
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- W2016029217 doi "https://doi.org/10.1016/s0167-577x(02)00903-5" @default.
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