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- W2016032249 abstract "The reactions of the potentially tridentate Schiff bases 2-[(2-hydroxyphenyl)iminomethyl]phenol (H 2 ono) and 2-(2-aminobenzylideneimino)phenol (H 3 onn) with trans -[ReOBr 3 (PPh 3 ) 2 ] were studied, and the complexes [Re III Br(PPh 3 ) 2 (ono)] ( 1 ) and [Re V Br(PPh 3 ) 2 (onn)]Br ( 2 ) were isolated. In 1 ono acts as a dianionic tridentate ligand, and in 2 onn is coordinated as a tridentate trianionic imido-imino-phenolate. The complex [Re I (CO) 3 (ons)(Hno)] was isolated from the reaction of [Re(CO) 5 Br] with 2-[(2-methylthio)benzylideneimino]phenol (Hons; Hno = 2-aminophenol), with ons coordinated as a bidentate chelate with a free SCH 3 group. These complexes were characterized by X-ray crystallography, NMR and IR spectroscopy." @default.
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- W2016032249 date "2010-03-01" @default.
- W2016032249 modified "2023-09-27" @default.
- W2016032249 title "Rhenium(I), (III) and (V) complexes of tridentate ONX (X=O, N, S)-donor Schiff bases" @default.
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- W2016032249 doi "https://doi.org/10.1016/j.poly.2010.01.013" @default.
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