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• W2016040544 abstract "Abstract Utilizing a photodiode array based spatial profiling spectrometer an extensive spatial characterization of the effect of an excess of an easily ionizabie element (EIE) on analyte emission in the inductively coupled plasma has been carried out. Significant spatial shifts, enhancements and depressions are induced on analyte emission by the presence of an EIE and it is shown that limited fixed height measurements may be seriously misleading with respect to interpretation of the effects of ElEs. In general, the addition of excess EIE enhances emission in the lower regions of the analyte channel for both atom and ion lines and in the upper regions of the analyte channel, emission intensity is depressed for both atom and ion species. Radial emission maps (for CaI and CaII) reveal that the enhancements low in the discharge occur along the off axis boundary of the analyte channel and the plasma discharge. Higher in the discharge CaI emission is generally depressed but CaII emission undergoes a central axis depression coupled with an off axis enhancement. Overall the data suggests that low in the discharge enhancement appears to be the result of increased collisional excitation and that higher in the discharge ambipolar diffusion may exert an influence on the spatial distribution of analyte species." @default.
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• W2016040544 date "1981-01-01" @default.
• W2016040544 modified "2023-09-26" @default.
• W2016040544 title "Interference from easily ionizable element matrices in inductively coupled plasma emission spectrometry—a spatial study" @default.
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• W2016040544 doi "https://doi.org/10.1016/0584-8547(81)80080-8" @default.
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