FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2016044520> ?p ?o ?g. }

• W2016044520 endingPage "112" @default.
• W2016044520 startingPage "105" @default.
• W2016044520 abstract "Abstract Ruthenium catalysts (5–15 wt.%) deposited on the high surface area magnesia ( S BET =94 m 2 /g), magnesium–aluminum spinel (96 m 2 /g) and magnesia–alumina mixture (Mg:Al=1:2 molar ratio, 65 m 2 /g) were characterized by the chemisorption techniques and tested in NH 3 synthesis. The chemisorption experiments (O 2 , CO) have shown that ruthenium is highly dispersed (FE=60–95%), even if the Ru loading is high (∼15 wt.%). The catalytic properties (TOF) of small ruthenium particles supported on Mg–Al spinel (the most effective unpromoted systems) proved to be only slightly, by 40%, more advantageous in NH 3 synthesis at 400 °C and 63 bar than the properties of particles supported on MgO–Al 2 O 3 mixture (the least active system), TOF over the former being roughly independent of the Ru crystallite size (1.0–1.5 nm). In contrast, the activities of the Ba-doped samples differed significantly, i.e. the TOF values (63 or 90 bar, 400 °C) over optimally promoted Ba–Ru/MgO were by four to eight times higher than those over Ba–Ru/Mg–Al spinel and by 30 times higher than over Ba–Ru/MgO–Al 2 O 3 mixture. The effect of the support on the Ba promotion is discussed. Under comparable conditions (400 °C, 63 bar, 8.5% NH 3 and 400 °C, 90 bar, 11% NH 3 ), the Ba–Ru/MgO catalyst (10 wt.% Ru) was by several times more active than multipromoted fused iron, the comparison being based on the volumetric reaction rates." @default.
• W2016044520 created "2016-06-24" @default.
• W2016044520 creator A5003335143 @default.
• W2016044520 creator A5004121752 @default.
• W2016044520 creator A5009343202 @default.
• W2016044520 creator A5070784615 @default.
• W2016044520 creator A5076434672 @default.
• W2016044520 creator A5081399110 @default.
• W2016044520 creator A5084470814 @default.
• W2016044520 date "2004-10-01" @default.
• W2016044520 modified "2023-10-09" @default.
• W2016044520 title "Ammonia synthesis over ruthenium catalysts supported on high surface area MgO and MgO–Al2O3 systems" @default.
• W2016044520 cites W103211297 @default.
• W2016044520 cites W1246012747 @default.
• W2016044520 cites W1501295953 @default.
• W2016044520 cites W1507804907 @default.
• W2016044520 cites W1575180290 @default.
• W2016044520 cites W1967407752 @default.
• W2016044520 cites W1967645513 @default.
• W2016044520 cites W1974131017 @default.
• W2016044520 cites W1986746711 @default.
• W2016044520 cites W1988161325 @default.
• W2016044520 cites W1997060154 @default.
• W2016044520 cites W2002290605 @default.
• W2016044520 cites W2004996050 @default.
• W2016044520 cites W2006003351 @default.
• W2016044520 cites W2009623205 @default.
• W2016044520 cites W2010528269 @default.
• W2016044520 cites W2010746168 @default.
• W2016044520 cites W2012504183 @default.
• W2016044520 cites W2019294362 @default.
• W2016044520 cites W2025063892 @default.
• W2016044520 cites W2032229148 @default.
• W2016044520 cites W2032345902 @default.
• W2016044520 cites W2033210562 @default.
• W2016044520 cites W2033438090 @default.
• W2016044520 cites W2035753916 @default.
• W2016044520 cites W2038362223 @default.
• W2016044520 cites W2044821861 @default.
• W2016044520 cites W2045085176 @default.
• W2016044520 cites W2046274457 @default.
• W2016044520 cites W2050010764 @default.
• W2016044520 cites W2051001531 @default.
• W2016044520 cites W2055806714 @default.
• W2016044520 cites W2057265919 @default.
• W2016044520 cites W2064197607 @default.
• W2016044520 cites W2071058899 @default.
• W2016044520 cites W2071895782 @default.
• W2016044520 cites W2078776027 @default.
• W2016044520 cites W2078888613 @default.
• W2016044520 cites W2085693694 @default.
• W2016044520 cites W2086537643 @default.
• W2016044520 cites W2088690150 @default.
• W2016044520 cites W2091164877 @default.
• W2016044520 cites W2092606752 @default.
• W2016044520 cites W2463412100 @default.
• W2016044520 cites W2953194890 @default.
• W2016044520 cites W327417995 @default.
• W2016044520 cites W4233735666 @default.
• W2016044520 cites W4240795023 @default.
• W2016044520 cites W4248960888 @default.
• W2016044520 cites W82341673 @default.
• W2016044520 cites W92880164 @default.
• W2016044520 doi "https://doi.org/10.1016/j.apcata.2004.06.020" @default.
• W2016044520 hasPublicationYear "2004" @default.
• W2016044520 type Work @default.
• W2016044520 sameAs 2016044520 @default.
• W2016044520 citedByCount "35" @default.
• W2016044520 countsByYear W20160445202012 @default.
• W2016044520 countsByYear W20160445202013 @default.
• W2016044520 countsByYear W20160445202014 @default.
• W2016044520 countsByYear W20160445202017 @default.
• W2016044520 countsByYear W20160445202018 @default.
• W2016044520 countsByYear W20160445202019 @default.
• W2016044520 countsByYear W20160445202020 @default.
• W2016044520 countsByYear W20160445202021 @default.
• W2016044520 countsByYear W20160445202022 @default.
• W2016044520 countsByYear W20160445202023 @default.
• W2016044520 crossrefType "journal-article" @default.
• W2016044520 hasAuthorship W2016044520A5003335143 @default.
• W2016044520 hasAuthorship W2016044520A5004121752 @default.
• W2016044520 hasAuthorship W2016044520A5009343202 @default.
• W2016044520 hasAuthorship W2016044520A5070784615 @default.
• W2016044520 hasAuthorship W2016044520A5076434672 @default.
• W2016044520 hasAuthorship W2016044520A5081399110 @default.
• W2016044520 hasAuthorship W2016044520A5084470814 @default.
• W2016044520 hasConcept C127413603 @default.
• W2016044520 hasConcept C161790260 @default.
• W2016044520 hasConcept C178790620 @default.
• W2016044520 hasConcept C179104552 @default.
• W2016044520 hasConcept C181258405 @default.
• W2016044520 hasConcept C185592680 @default.
• W2016044520 hasConcept C192562407 @default.
• W2016044520 hasConcept C2776382133 @default.
• W2016044520 hasConcept C42360764 @default.
• W2016044520 hasConcept C555196967 @default.
• W2016044520 hasConceptScore W2016044520C127413603 @default.
• W2016044520 hasConceptScore W2016044520C161790260 @default.

• next