FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2016047020> ?p ?o ?g. }

• W2016047020 endingPage "16209" @default.
• W2016047020 startingPage "16209" @default.
• W2016047020 abstract "An ionic crystal [Cr3O(OOCCF3)6(H2O)3]3[α-PW12O40]·8CH3COCH3·8H2O·CHCl3 [Ia] was synthesized by the complexation of a fluorine-substituted macrocation with a phosphododecatungstate. Compound Ia possessed a layered structure with an interlayer distance of ca. 3.5 Å, and the inner surface of the layer was decorated with CF3 groups of the macrocations. The solvent molecules (acetone and chloroform) spontaneously desorbed and exchanged with water under an ambient atmosphere and a hydrated phase [Cr3O(OOCCF3)6(H2O)3]3[α-PW12O40]·25H2O [Ib] was formed. The water molecules were partially desorbed by the treatment of Ibin vacuo or under a dry N2 or He flow at 298–303 K, and [Cr3O(OOCCF3)6(H2O)3]3[α-PW12O40]·15H2O [Ic] was formed. The powder XRD pattern of Ic well agreed with that calculated for Ia, showing that the structure was maintained after the exchange and partial desorption of guests. Compound Ic sorbed CO2 and unsaturated hydrocarbons, while saturated hydrocarbons such as ethane and methane were almost excluded despite the similar kinetic diameters. Acetylene/methane, CO2/methane, and ethylene/ethane sorption ratios were 13, 15, and 4.9, respectively, at 198 K and 100 kPa. Typical Monte Carlo-based optimized geometries of acetylene and CO2 showed different alignments in the structure of Ic despite the similar amounts of sorption and molecular sizes. Acetylene and CO2 were aligned mainly parallel and perpendicular, respectively, to the layer, which is probably due to the differences in the electron density distributions of the HOMO orbitals." @default.
• W2016047020 created "2016-06-24" @default.
• W2016047020 creator A5012322330 @default.
• W2016047020 creator A5069123807 @default.
• W2016047020 creator A5078700411 @default.
• W2016047020 creator A5090955686 @default.
• W2016047020 date "2013-01-01" @default.
• W2016047020 modified "2023-10-15" @default.
• W2016047020 title "Highly selective sorption and unique packing geometries of unsaturated hydrocarbons and CO2 in a fluorine-substituted organic–inorganic ionic crystal" @default.
• W2016047020 cites W1650728208 @default.
• W2016047020 cites W1966750682 @default.
• W2016047020 cites W1978008105 @default.
• W2016047020 cites W1978030794 @default.
• W2016047020 cites W1978894639 @default.
• W2016047020 cites W1981017446 @default.
• W2016047020 cites W1981368803 @default.
• W2016047020 cites W1986022082 @default.
• W2016047020 cites W1989036019 @default.
• W2016047020 cites W1995630572 @default.
• W2016047020 cites W2004260680 @default.
• W2016047020 cites W2007424415 @default.
• W2016047020 cites W2010448625 @default.
• W2016047020 cites W2020638099 @default.
• W2016047020 cites W2022415942 @default.
• W2016047020 cites W2030841140 @default.
• W2016047020 cites W2030971064 @default.
• W2016047020 cites W2040563720 @default.
• W2016047020 cites W2042362062 @default.
• W2016047020 cites W2056760934 @default.
• W2016047020 cites W2062904068 @default.
• W2016047020 cites W2065194628 @default.
• W2016047020 cites W2070178225 @default.
• W2016047020 cites W2075731109 @default.
• W2016047020 cites W2080507319 @default.
• W2016047020 cites W2083172037 @default.
• W2016047020 cites W2086932788 @default.
• W2016047020 cites W2089888905 @default.
• W2016047020 cites W2099486431 @default.
• W2016047020 cites W2100697536 @default.
• W2016047020 cites W2101713007 @default.
• W2016047020 cites W2110249624 @default.
• W2016047020 cites W2125053394 @default.
• W2016047020 cites W2130831264 @default.
• W2016047020 cites W2137459371 @default.
• W2016047020 cites W2145880313 @default.
• W2016047020 cites W2146393076 @default.
• W2016047020 cites W2151985601 @default.
• W2016047020 cites W2155253046 @default.
• W2016047020 cites W2313618219 @default.
• W2016047020 cites W2314633702 @default.
• W2016047020 cites W2325700600 @default.
• W2016047020 cites W2330151227 @default.
• W2016047020 cites W2336043143 @default.
• W2016047020 cites W2952376987 @default.
• W2016047020 cites W2605749030 @default.
• W2016047020 doi "https://doi.org/10.1039/c3dt51458g" @default.
• W2016047020 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24091551" @default.
• W2016047020 hasPublicationYear "2013" @default.
• W2016047020 type Work @default.
• W2016047020 sameAs 2016047020 @default.
• W2016047020 citedByCount "15" @default.
• W2016047020 countsByYear W20160470202014 @default.
• W2016047020 countsByYear W20160470202015 @default.
• W2016047020 countsByYear W20160470202016 @default.
• W2016047020 countsByYear W20160470202017 @default.
• W2016047020 countsByYear W20160470202018 @default.
• W2016047020 countsByYear W20160470202019 @default.
• W2016047020 countsByYear W20160470202021 @default.
• W2016047020 countsByYear W20160470202023 @default.
• W2016047020 crossrefType "journal-article" @default.
• W2016047020 hasAuthorship W2016047020A5012322330 @default.
• W2016047020 hasAuthorship W2016047020A5069123807 @default.
• W2016047020 hasAuthorship W2016047020A5078700411 @default.
• W2016047020 hasAuthorship W2016047020A5090955686 @default.
• W2016047020 hasConcept C115624301 @default.
• W2016047020 hasConcept C145148216 @default.
• W2016047020 hasConcept C147789679 @default.
• W2016047020 hasConcept C150394285 @default.
• W2016047020 hasConcept C162711632 @default.
• W2016047020 hasConcept C178790620 @default.
• W2016047020 hasConcept C179104552 @default.
• W2016047020 hasConcept C185592680 @default.
• W2016047020 hasConcept C199360897 @default.
• W2016047020 hasConcept C2182769 @default.
• W2016047020 hasConcept C2777517455 @default.
• W2016047020 hasConcept C2781285689 @default.
• W2016047020 hasConcept C32909587 @default.
• W2016047020 hasConcept C41008148 @default.
• W2016047020 hasConcept C516920438 @default.
• W2016047020 hasConcept C58445606 @default.
• W2016047020 hasConcept C8010536 @default.
• W2016047020 hasConceptScore W2016047020C115624301 @default.
• W2016047020 hasConceptScore W2016047020C145148216 @default.
• W2016047020 hasConceptScore W2016047020C147789679 @default.
• W2016047020 hasConceptScore W2016047020C150394285 @default.
• W2016047020 hasConceptScore W2016047020C162711632 @default.
• W2016047020 hasConceptScore W2016047020C178790620 @default.
• W2016047020 hasConceptScore W2016047020C179104552 @default.

• next