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- W2016047030 abstract "Classical and nonclassical Ru (II) and Os (II) polyhydride complexes stabilized by the tripodal polydentate ligand P (CH2CH2PPh2)3 (PP3) catalyze the regio- and stereo-selective dimerization of 1-alkynes to the corresponding (Z)-1,4-disubstituted butenynes. Reaction mechanisms accounting for the catalytic cycles are proposed. Irrespective of the nature of the hydride ligand (classical vs nonclassical) vinylidene complexes are the immediate precursors to the C-C bond forming step." @default.
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- W2016047030 date "1996-01-01" @default.
- W2016047030 modified "2023-09-29" @default.
- W2016047030 title "REGIO- AND STEREOSELECTIVE DIMERIZATION OF 1-ALKYNES CATALYZED BY CLASSICAL AND NONCLASSICAL RUTHENIUM AND OSMIUM POLYHYDRIDO COMPLEXES" @default.
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- W2016047030 doi "https://doi.org/10.3363/prb1992.6.0_151" @default.
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