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- W2016052188 abstract "A synthetic strategy has been developed for preparation of NLO chromophores with all the π-conjugated methine groups incorporated into plane-rigidified, fused, six-membered rings. The comparison of the rigidified chromophores to the analogous nonrigid chromophores shows that the configuration-locking methods provide a dramatic enhancement of molecular thermal stability. The data from UV−vis spectroscopy and X-ray crystallography reveal that the rigidity of the annulated rings does not diminish the planarity and the electron delocalization efficiency of the polyenic chain." @default.
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- W2016052188 date "1998-09-16" @default.
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- W2016052188 title "Nonlinear Optical Chromophores with Configuration-Locked Polyenes Possessing Enhanced Thermal Stability and Chemical Stability" @default.
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