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- W2016054189 abstract "Abstract NOE and T 1 proton measurements were carried out in order to determine unambiguously the Z and E configurations of some CF 3 ‐trisubstituted vinylic compounds (HCRCR′CF 3 ). The β‐ethylenic carbon in olefins, enol ethers and enamines is always more strongly coupled to CF 3 in the cis compound (CF 3 and the vinylic proton cis to each other): | 3 J (CF)| cis > | 3 J (CF)| trans . This observation, in addition to the already known higher shielding of 19 F NMR signal in the cis isomer, allows the safe assignments of Z and E isomers even when only one is obtained, regardless of the nature of R and R′." @default.
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- W2016054189 date "1991-07-01" @default.
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- W2016054189 title "Determination ofZ andE configurations in trifluoromethylated vinyl compounds:3J(CF) coupling constants as a criterion for configurational assignments" @default.
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- W2016054189 doi "https://doi.org/10.1002/mrc.1260290707" @default.
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