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- W2016054235 abstract "(1R)-2-endo-(Dimethylamino)methyl-2-exo-methoxy-3-endo-camphor- ylselenenyl bromide and its 2-endo-(pyrrolidenyl)methyl analogue were prepared from (1R)-2-endo-acetamidomethyl-2-exo-hydroxy-3-endo-camphoryl diselenide. Both compounds showed an unusual lack of reactivity in electrophilic oxyselenenylation and cyclization reactions that are typical of other selenenyl bromides. X-ray crystallography indicated that both compounds have strong N─Se interactions, with N─Se interatomic distances of ca. 2.1 A, which diminish the electrophilic character of the selenium atom." @default.
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- W2016054235 date "2004-12-01" @default.
- W2016054235 modified "2023-10-16" @default.
- W2016054235 title "PREPARATION AND X-RAY CRYSTAL STRUCTURES OF TWO ALIPHATIC SELENENYL BROMIDES STABILIZED BY N─SE COORDINATION" @default.
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- W2016054235 doi "https://doi.org/10.1080/10426500490494543" @default.
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