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- W2016056182 abstract "The cis-trans photoisomerization of 2-naphthylvinylenethioamide was investigated in ethanol and benzene solutions at various excitation wavelengths. The quantum yields varied in an irregular manner with the excitation wavelength; this unusual result was attributed to the existence of rotamers, each decaying with its own characteristics. The trans → cis quantum yield decreased with increasing quencher concentration in the presence of azulene, whereas the cis → trans yield increased. The sum of the two quantum yields was constant. Benzophenone sensitized the photoisomerization such that the same quantum yield (0.5) was obtained for the trans → cis and the cis → trans processes. The results were interpreted on the basis of an isomerization scheme in which the process proceeded through a triplet state directly quenched to the trans isomer by azulene." @default.
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- W2016056182 date "1983-01-01" @default.
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- W2016056182 title "Mechanism of photochemical reactions of arylvinylenethioamides III: The photoisomerization of 2-naphthylvinylenethioamide" @default.
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- W2016056182 doi "https://doi.org/10.1016/0047-2670(83)80060-4" @default.
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