FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2016056554> ?p ?o ?g. }

• W2016056554 endingPage "153" @default.
• W2016056554 startingPage "133" @default.
• W2016056554 abstract "In this study a model that allows the qualitative prediction of polymer thermal diffusion coefficients from polymer-solvent interaction parameters is presented. The Flory-Huggins lattice theory served as a starting point for the thermal diffusion model. From this model it follows that D T is determined by the temperature dependence of the polymer-solvent interaction parameter ( h ), the segmental mobility of the polymer chain, and the polymer concentration. In agreement with literature data, the model predicts that D T is independent of the molecular mass of the polymer, D T increases with temperature, and D T is strongly dependent on the interaction between the polymer and the solvent. Furthermore, it follows from the model that D T should decrease with concentration. A good qualitative agreement with experimental data has been found. In order to study the potentials of the model, the D T values of polystyrene (PS) in several solvents were predicted. The required temperature-dependent polymer-solvent interaction parameters were calculated from Hildebrand's solubility parameters of the polymer and of the solvent. The solvent's solubility parameters were estimated using Lee and Kesler's generalized thermodynamic equations of state. The polymer solubility parameters were taken from the literature. Lack of data complicated the comparison. However, a good agreement for PS in THF, MEK, dioxane, and cyclohexane was found. Thermal diffusion values predicted for PS in several aromatic solvents were, however, significantly low. Still, the overall result is satisfactory considering the fact that the Flory-Huggins theory is a highly simplified polymer-solvent theory that was never intended to be used for quantitative purposes. Polymer thermal diffusion model Thermal field-flow fractionation Polymer-solvent interaction parameter Thermal diffusion forced Rayleigh scattering" @default.
• W2016056554 created "2016-06-24" @default.
• W2016056554 creator A5014158471 @default.
• W2016056554 creator A5038079536 @default.
• W2016056554 creator A5048449675 @default.
• W2016056554 date "2003-01-01" @default.
• W2016056554 modified "2023-10-10" @default.
• W2016056554 title "Prediction of Polymer Thermal Diffusion Coefficients from Polymer-Solvent Interaction Parameters: Comparison with Thermal Field Flow Fractionation and Thermal Diffusion Forced Rayleigh Scattering Experiments" @default.
• W2016056554 cites W1964730829 @default.
• W2016056554 cites W1982188954 @default.
• W2016056554 cites W1988493049 @default.
• W2016056554 cites W1991917924 @default.
• W2016056554 cites W1999675138 @default.
• W2016056554 cites W2000086134 @default.
• W2016056554 cites W2000605076 @default.
• W2016056554 cites W2002370865 @default.
• W2016056554 cites W2002674056 @default.
• W2016056554 cites W2003031120 @default.
• W2016056554 cites W2007535160 @default.
• W2016056554 cites W2009868517 @default.
• W2016056554 cites W2012314954 @default.
• W2016056554 cites W2020092873 @default.
• W2016056554 cites W2022392977 @default.
• W2016056554 cites W2026644020 @default.
• W2016056554 cites W2027286075 @default.
• W2016056554 cites W2032448967 @default.
• W2016056554 cites W2034993526 @default.
• W2016056554 cites W2042887747 @default.
• W2016056554 cites W2043477570 @default.
• W2016056554 cites W2045601639 @default.
• W2016056554 cites W2047202152 @default.
• W2016056554 cites W2049987978 @default.
• W2016056554 cites W2053530509 @default.
• W2016056554 cites W2054707937 @default.
• W2016056554 cites W2055886314 @default.
• W2016056554 cites W2057997046 @default.
• W2016056554 cites W2063253218 @default.
• W2016056554 cites W2065822591 @default.
• W2016056554 cites W2073777011 @default.
• W2016056554 cites W2074804670 @default.
• W2016056554 cites W2079189128 @default.
• W2016056554 cites W2083835207 @default.
• W2016056554 cites W2095202046 @default.
• W2016056554 cites W2105442824 @default.
• W2016056554 cites W2115555735 @default.
• W2016056554 cites W2123871949 @default.
• W2016056554 cites W2134354851 @default.
• W2016056554 cites W2139797052 @default.
• W2016056554 cites W2166603099 @default.
• W2016056554 cites W2167653830 @default.
• W2016056554 cites W2316138218 @default.
• W2016056554 cites W2319836439 @default.
• W2016056554 cites W2325147537 @default.
• W2016056554 cites W2329475149 @default.
• W2016056554 cites W2438368441 @default.
• W2016056554 cites W2504013430 @default.
• W2016056554 cites W4230344959 @default.
• W2016056554 cites W2077135108 @default.
• W2016056554 doi "https://doi.org/10.1080/10236660304888" @default.
• W2016056554 hasPublicationYear "2003" @default.
• W2016056554 type Work @default.
• W2016056554 sameAs 2016056554 @default.
• W2016056554 citedByCount "23" @default.
• W2016056554 countsByYear W20160565542012 @default.
• W2016056554 countsByYear W20160565542014 @default.
• W2016056554 countsByYear W20160565542016 @default.
• W2016056554 countsByYear W20160565542019 @default.
• W2016056554 countsByYear W20160565542020 @default.
• W2016056554 countsByYear W20160565542021 @default.
• W2016056554 countsByYear W20160565542022 @default.
• W2016056554 countsByYear W20160565542023 @default.
• W2016056554 crossrefType "journal-article" @default.
• W2016056554 hasAuthorship W2016056554A5014158471 @default.
• W2016056554 hasAuthorship W2016056554A5038079536 @default.
• W2016056554 hasAuthorship W2016056554A5048449675 @default.
• W2016056554 hasConcept C100293340 @default.
• W2016056554 hasConcept C121332964 @default.
• W2016056554 hasConcept C147789679 @default.
• W2016056554 hasConcept C155574463 @default.
• W2016056554 hasConcept C159985019 @default.
• W2016056554 hasConcept C178790620 @default.
• W2016056554 hasConcept C185592680 @default.
• W2016056554 hasConcept C188027245 @default.
• W2016056554 hasConcept C192562407 @default.
• W2016056554 hasConcept C2777922577 @default.
• W2016056554 hasConcept C2778237882 @default.
• W2016056554 hasConcept C2780471494 @default.
• W2016056554 hasConcept C37668627 @default.
• W2016056554 hasConcept C521977710 @default.
• W2016056554 hasConcept C69357855 @default.
• W2016056554 hasConcept C97355855 @default.
• W2016056554 hasConcept C98765843 @default.
• W2016056554 hasConceptScore W2016056554C100293340 @default.
• W2016056554 hasConceptScore W2016056554C121332964 @default.
• W2016056554 hasConceptScore W2016056554C147789679 @default.
• W2016056554 hasConceptScore W2016056554C155574463 @default.
• W2016056554 hasConceptScore W2016056554C159985019 @default.
• W2016056554 hasConceptScore W2016056554C178790620 @default.

• next