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• W2016057421 abstract "Abstract First examples of the coordination chemistry of the As 4 S 3 cage were obtained from solutions of As 4 S 3 · M(CO) 5 (M = Cr, W) in CH 2 Cl 2 and CuCl n in CH 3 CN ( n = 1) or CH 3 OH ( n = 2) through interdiffusion techniques. The compounds (As 4 S 3 )(CuCl) n ( 1 : n = 1; 2 : n = 2) exhibit Cu coordination exclusively through the sulfur bridges. The crystal structure of 1 containsa saw‐like [CuCl] backbone to which As 4 S 3 cages are alternately fixed on both sides through two of their sulfur atoms. The crystal structure of 2 is built up of sheets, in which As 4 S 3 molecules are connected by folded four‐membered Cu 2 Cl 2 rings through all sulfur atoms. Comparative Raman spectra of As 4 S 3 and 1 indicate significant interactions between the cage S atoms and Cu.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)" @default.
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• W2016057421 date "2008-11-28" @default.
• W2016057421 modified "2023-09-26" @default.
• W2016057421 title "Novel Coordination Modes for E₄S₃ Cage Molecules (E = P, As) in Unprecedented Quaternary As₄S₃(CuCl)<i>_n</i> (<i>n</i> = 1,2) Solid‐State Phases" @default.
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• W2016057421 doi "https://doi.org/10.1002/ejic.200801015" @default.
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