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- W2016063295 abstract "Reaction of the thioether macrocycles TT[9]OC and Me2TT[9]OC with Ag+ salts in a 1:1 ratio produces unique tetrameric cations containing an octagonal [Ag4S4]4+ cavity. The X-ray crystal structures of three of these aggregates {[AgL][X]}4 (X =BF4−, L = TT[9]OC; X = CF3SO3−, L = TT[9]OC; X = BF4−, L = Me2TT[9]OC) were determined. In each case, the thiacyclophane ligand bonds in a facial coordination mode to one Ag(I) ion with the central S-donor bridging to the next Ag(I) ion. This completes a pseudotetrahedral geometry and results in cyclic tetramers with a [AgS]44+ octagonal core. Each structure has two symmetry related anions (BF4− or CF3SO3− included over the opposing faces of the large tetracationic cavity. {[Ag(TT[9]OC)][BF4]}4·2(MeCN): C52H70B4F16N2S12, P21c, a=14.525(7), b=16.703(11), c = 16.250(6) Å, β = 115.54(3)°, V = 3557(6)Å3 and Z=2. {[Ag(TT[9]OC)][CF3SO3]}4: C52H64Ag4F12O12S16, P21c, a=12.308(2), b=23.381(4), c=14.018(2) A, β = 113.30(1)°, V = 3705(5)Å3 and Z=2. {[Ag(Me2[9]OC)][BF4]}4·2(MeCN): C60H86Ag4B4F16N2S12, P21c, a=14.878(8), b=17.356(7), c = ]6.804([1) Å, P = 114.95(4)°, V = 3934(4) A3 and Z = 2." @default.
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- W2016063295 date "1996-05-01" @default.
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- W2016063295 title "Tetranuclear Ag(I) complexes with an octagonal Ag4S4 core: building large structures from small macrocycles" @default.
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- W2016063295 doi "https://doi.org/10.1016/0020-1693(96)05067-0" @default.
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