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- W2016064652 abstract "Reactions of α-S-cyanothioketones 6a-c with malononitrile were observed to form 2-(thiazol- 2(3H)-ylidene)malononitrile derivatives 7a-c. The thiazole products readily react with aromatic diazonium salts to yield 2-(5-phenylazo-3H-thiazol-2-ylidene)-malononitrile derivatives 8a-c. The malononitrile derivative 8c undergoes a condensation with DMF/DMA to yield thiazolo(5,4- c)pyridazine 12. Reactions of 7a-c with hydrazine hydrate leads to the generation of diaminopyrazoles 9a-c, which react with enaminone 13 to yield the corresponding thiazolylpyrazolo(1,5-a)pyrimidines 14. In addition, reaction of the malononitrile derivative 8a with benzenediazonium chloride readily affords the coupling product 10." @default.
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- W2016064652 date "2010-05-29" @default.
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- W2016064652 title "Polyfunctional heteroaromatics: a route to dicyanomethylene thiazoles based on the reaction of α-thiocyanatoketones with malononitrile" @default.
- W2016064652 doi "https://doi.org/10.3998/ark.5550190.0011.217" @default.
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