Matches in SemOpenAlex for { <https://semopenalex.org/work/W2016065487> ?p ?o ?g. }
- W2016065487 endingPage "239" @default.
- W2016065487 startingPage "235" @default.
- W2016065487 abstract "Three porous Al-BTCs (BTC: benzenetricarboxylate) have been synthesized in wide reaction conditions including heating methods (conventional electric and microwave heating) and reaction time. It has been found that an Al-BTC called MIL-100 converts into another phase (MIL-110) with increasing time and eventually a different phase (MIL-96) is observed. This phase-conversion is the first observation of the possibility to synthesize three MOFs from the very same reactant mixtures, and may be explained with the relative stability of the Al-BTCs (MIL-96 > MIL-110 > MIL-100) since the stability of a porous material may increase with decreasing porosity or pore size of the phases. The inter-conversion of a less stable Al-BTC into a more stable one is carried out via recombination of the degraded precursors. Moreover, due to the advantage of rapid crystallization of microwave heating, it can be found that microwave synthesis selectively leads to highly porous materials like MIL-100 or MIL-110. This phase-selective synthesis with microwaves is similar to the synthesis of another MOFs (Cr-BDCs) and aluminophosphates, and may lead to a new way to synthesize highly porous (unstable) materials." @default.
- W2016065487 created "2016-06-24" @default.
- W2016065487 creator A5023276622 @default.
- W2016065487 creator A5031552790 @default.
- W2016065487 creator A5052274244 @default.
- W2016065487 creator A5070372188 @default.
- W2016065487 creator A5078137984 @default.
- W2016065487 date "2012-04-01" @default.
- W2016065487 modified "2023-10-17" @default.
- W2016065487 title "Phase-selective synthesis and phase-conversion of porous aluminum-benzenetricarboxylates with microwave irradiation" @default.
- W2016065487 cites W1820345752 @default.
- W2016065487 cites W1967109824 @default.
- W2016065487 cites W1968790915 @default.
- W2016065487 cites W1969420916 @default.
- W2016065487 cites W1969627970 @default.
- W2016065487 cites W1975034245 @default.
- W2016065487 cites W1976097044 @default.
- W2016065487 cites W1977647650 @default.
- W2016065487 cites W1988320363 @default.
- W2016065487 cites W1988855306 @default.
- W2016065487 cites W1993146835 @default.
- W2016065487 cites W1995810362 @default.
- W2016065487 cites W1996352962 @default.
- W2016065487 cites W1999430010 @default.
- W2016065487 cites W2004550299 @default.
- W2016065487 cites W2006520672 @default.
- W2016065487 cites W2006953965 @default.
- W2016065487 cites W2009565017 @default.
- W2016065487 cites W2012363955 @default.
- W2016065487 cites W2016143512 @default.
- W2016065487 cites W2022167379 @default.
- W2016065487 cites W2033208051 @default.
- W2016065487 cites W2037430787 @default.
- W2016065487 cites W2039764100 @default.
- W2016065487 cites W2041461900 @default.
- W2016065487 cites W2041998035 @default.
- W2016065487 cites W2045908830 @default.
- W2016065487 cites W2046741458 @default.
- W2016065487 cites W2051536359 @default.
- W2016065487 cites W2057756143 @default.
- W2016065487 cites W2067866527 @default.
- W2016065487 cites W2073100034 @default.
- W2016065487 cites W2077558855 @default.
- W2016065487 cites W2078678890 @default.
- W2016065487 cites W2081350764 @default.
- W2016065487 cites W2083318454 @default.
- W2016065487 cites W2083645978 @default.
- W2016065487 cites W2087999018 @default.
- W2016065487 cites W2088362985 @default.
- W2016065487 cites W2093815467 @default.
- W2016065487 cites W2095853776 @default.
- W2016065487 cites W2098292174 @default.
- W2016065487 cites W2099486431 @default.
- W2016065487 cites W2099672171 @default.
- W2016065487 cites W2106029391 @default.
- W2016065487 cites W2115764422 @default.
- W2016065487 cites W2118110100 @default.
- W2016065487 cites W2144504794 @default.
- W2016065487 cites W2155113974 @default.
- W2016065487 cites W2155906217 @default.
- W2016065487 cites W2156487970 @default.
- W2016065487 cites W2170811673 @default.
- W2016065487 cites W2313665937 @default.
- W2016065487 cites W2315416499 @default.
- W2016065487 cites W2858547974 @default.
- W2016065487 cites W794200257 @default.
- W2016065487 doi "https://doi.org/10.1016/j.micromeso.2011.11.025" @default.
- W2016065487 hasPublicationYear "2012" @default.
- W2016065487 type Work @default.
- W2016065487 sameAs 2016065487 @default.
- W2016065487 citedByCount "49" @default.
- W2016065487 countsByYear W20160654872012 @default.
- W2016065487 countsByYear W20160654872013 @default.
- W2016065487 countsByYear W20160654872014 @default.
- W2016065487 countsByYear W20160654872015 @default.
- W2016065487 countsByYear W20160654872016 @default.
- W2016065487 countsByYear W20160654872017 @default.
- W2016065487 countsByYear W20160654872018 @default.
- W2016065487 countsByYear W20160654872019 @default.
- W2016065487 countsByYear W20160654872020 @default.
- W2016065487 countsByYear W20160654872021 @default.
- W2016065487 countsByYear W20160654872022 @default.
- W2016065487 countsByYear W20160654872023 @default.
- W2016065487 crossrefType "journal-article" @default.
- W2016065487 hasAuthorship W2016065487A5023276622 @default.
- W2016065487 hasAuthorship W2016065487A5031552790 @default.
- W2016065487 hasAuthorship W2016065487A5052274244 @default.
- W2016065487 hasAuthorship W2016065487A5070372188 @default.
- W2016065487 hasAuthorship W2016065487A5078137984 @default.
- W2016065487 hasConcept C105569014 @default.
- W2016065487 hasConcept C121332964 @default.
- W2016065487 hasConcept C127413603 @default.
- W2016065487 hasConcept C159985019 @default.
- W2016065487 hasConcept C178790620 @default.
- W2016065487 hasConcept C185592680 @default.
- W2016065487 hasConcept C192562407 @default.
- W2016065487 hasConcept C203036418 @default.
- W2016065487 hasConcept C2984548686 @default.