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- W2016066635 abstract "Hydrogenation rates of isomeric methyl octadecenoates were compared by reducing mixtures containing a small weight of one radioactively labeled isomer and a much larger weight of another unlabeled isomer. As hydrogenation proceeded, samples were removed for analysis by a gas chromatograph, coupled with an ionization chamber so that mass peaks measured reduction of the unlabeled isomer and radioactive peaks of the labeled isomer. The ratio of hydrogenation rates best fitting these data was calculated with a digital computer. Reductions were made at atmospheric pressure generally with either nickel at 140C or platinum at 50C. A few were made with palladium at 50C. Methyl oleate hydrogenated more rapidly than methyl elaidate and thecis-15-isomer more rapidly than oleate. Other variations among the positionalcis isomers investigated were small." @default.
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- W2016066635 date "1971-05-01" @default.
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- W2016066635 title "Competitive hydrogenation rates of isomeric methyl octadecenoates" @default.
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