FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2016068704> ?p ?o ?g. }

• W2016068704 endingPage "14779" @default.
• W2016068704 startingPage "14766" @default.
• W2016068704 abstract "We studied the adsorption structures and reactions of C6 hydrocarbon molecules (cyclohexene, cyclohexane, 1-methylcyclohexene, n-hexane, 2- and 3-methylpentanes, and 1-hexene) on Pt(111) using sum frequency generation (SFG) vibrational spectroscopy. The experiments were performed in the presence and absence of excess hydrogen and as a function of temperature. Upon cyclohexene adsorption on Pt(111) at 1.5 Torr, 1,3- and 1,4-cyclohexadienes and π-allyl C6H9 were observed in the presence of excess hydrogen. Cyclohexane adsorption at 1.5 Torr resulted in the formation of cyclohexyl on the surface in the presence of excess hydrogen but π-allyl C6H9 in absence of excess hydrogen. 1-Methylcyclohexene formed methylcyclohexenyl on the surface only in the presence of excess hydrogen. n-Hexane and 3-methylpentane adsorbed molecularly on Pt(111) at 296 K in the presence of excess hydrogen. 2-Methylpentane and 1-hexene were readily dehydrogenated to form metallacyclobutane and hexylidyne even at 296 K, regardless of the presence of excess hydrogen. n-Hexane was dehydrogenated to form hexylidyne or metallacyclic species at high temperature in the presence of excess hydrogen. Hexylidyne and metallacyclic species were also main surface intermediates in dehydrogenation of 2- and 3-methylpentane. The absence of excess hydrogen induced dehydrocyclization of n-hexane to form π-allyl c-C6H9. On the basis of the SFG results, the mechanism of the n-hexane conversion to benzene is discussed." @default.
• W2016068704 created "2016-06-24" @default.
• W2016068704 creator A5058666235 @default.
• W2016068704 creator A5075941013 @default.
• W2016068704 creator A5085378812 @default.
• W2016068704 date "2004-07-28" @default.
• W2016068704 modified "2023-09-23" @default.
• W2016068704 title "The Structures and Reactions of Linear and Cyclic C₆Hydrocarbons Adsorbed on the Pt(111) Crystal Surface Studied by Sum Frequency Generation Vibrational Spectroscopy: Pressure, Temperature, and H₂Coadsorption Effects" @default.
• W2016068704 cites W1964185990 @default.
• W2016068704 cites W1966017072 @default.
• W2016068704 cites W1967529531 @default.
• W2016068704 cites W1975911253 @default.
• W2016068704 cites W1976091770 @default.
• W2016068704 cites W1976242732 @default.
• W2016068704 cites W1976521205 @default.
• W2016068704 cites W1979152651 @default.
• W2016068704 cites W1981192368 @default.
• W2016068704 cites W1983416278 @default.
• W2016068704 cites W1987540925 @default.
• W2016068704 cites W1987897492 @default.
• W2016068704 cites W1990658138 @default.
• W2016068704 cites W1993821685 @default.
• W2016068704 cites W1996388883 @default.
• W2016068704 cites W1999989196 @default.
• W2016068704 cites W2001013852 @default.
• W2016068704 cites W2005811636 @default.
• W2016068704 cites W2005982046 @default.
• W2016068704 cites W2013382132 @default.
• W2016068704 cites W2016538218 @default.
• W2016068704 cites W2016676999 @default.
• W2016068704 cites W2017216038 @default.
• W2016068704 cites W2020941652 @default.
• W2016068704 cites W2021079605 @default.
• W2016068704 cites W2023562360 @default.
• W2016068704 cites W2025839981 @default.
• W2016068704 cites W2029301305 @default.
• W2016068704 cites W2035005406 @default.
• W2016068704 cites W2035508510 @default.
• W2016068704 cites W2036647286 @default.
• W2016068704 cites W2047501009 @default.
• W2016068704 cites W2049966494 @default.
• W2016068704 cites W2054953600 @default.
• W2016068704 cites W2055465627 @default.
• W2016068704 cites W2059840509 @default.
• W2016068704 cites W2060609035 @default.
• W2016068704 cites W2062377703 @default.
• W2016068704 cites W2069366616 @default.
• W2016068704 cites W2071890513 @default.
• W2016068704 cites W2079910591 @default.
• W2016068704 cites W2079914346 @default.
• W2016068704 cites W2081180002 @default.
• W2016068704 cites W2111201663 @default.
• W2016068704 cites W2140764005 @default.
• W2016068704 cites W2151486069 @default.
• W2016068704 cites W2163354936 @default.
• W2016068704 cites W2164701295 @default.
• W2016068704 cites W2166209808 @default.
• W2016068704 cites W2313318573 @default.
• W2016068704 cites W2949962129 @default.
• W2016068704 cites W3036783547 @default.
• W2016068704 cites W4252937701 @default.
• W2016068704 doi "https://doi.org/10.1021/jp048238n" @default.
• W2016068704 hasPublicationYear "2004" @default.
• W2016068704 type Work @default.
• W2016068704 sameAs 2016068704 @default.
• W2016068704 citedByCount "35" @default.
• W2016068704 countsByYear W20160687042012 @default.
• W2016068704 countsByYear W20160687042013 @default.
• W2016068704 countsByYear W20160687042014 @default.
• W2016068704 countsByYear W20160687042015 @default.
• W2016068704 countsByYear W20160687042017 @default.
• W2016068704 countsByYear W20160687042018 @default.
• W2016068704 countsByYear W20160687042023 @default.
• W2016068704 crossrefType "journal-article" @default.
• W2016068704 hasAuthorship W2016068704A5058666235 @default.
• W2016068704 hasAuthorship W2016068704A5075941013 @default.
• W2016068704 hasAuthorship W2016068704A5085378812 @default.
• W2016068704 hasConcept C119889771 @default.
• W2016068704 hasConcept C121332964 @default.
• W2016068704 hasConcept C147789679 @default.
• W2016068704 hasConcept C150394285 @default.
• W2016068704 hasConcept C153642686 @default.
• W2016068704 hasConcept C161790260 @default.
• W2016068704 hasConcept C178790620 @default.
• W2016068704 hasConcept C185592680 @default.
• W2016068704 hasConcept C2777077568 @default.
• W2016068704 hasConcept C2777207669 @default.
• W2016068704 hasConcept C2777691172 @default.
• W2016068704 hasConcept C2778237882 @default.
• W2016068704 hasConcept C2779484182 @default.
• W2016068704 hasConcept C512968161 @default.
• W2016068704 hasConcept C58364064 @default.
• W2016068704 hasConcept C62520636 @default.
• W2016068704 hasConcept C75473681 @default.
• W2016068704 hasConceptScore W2016068704C119889771 @default.
• W2016068704 hasConceptScore W2016068704C121332964 @default.
• W2016068704 hasConceptScore W2016068704C147789679 @default.
• W2016068704 hasConceptScore W2016068704C150394285 @default.

• next