FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2016072028> ?p ?o ?g. }

• W2016072028 endingPage "2061" @default.
• W2016072028 startingPage "2051" @default.
• W2016072028 abstract "Fundamental studies have greatly improved our understanding of electrospray, including the underlying electrochemical reactions. Generally regarded as disadvantageous, we have recently shown that corona discharge (CD) can be used as an effective method to create a radical cation species [M]+., thus optimizing the electrochemical reactions that occur on the surface of the stainless steel (SS) electrospray capillary tip. This technique is known as CD initiated electrochemical ionization (CD-ECI). Here, we report on the fundamental studies using CD-ECI to induce analytically useful in-source fragmentation of a range of molecules that complex transition metals. Compounds that have been selectively fragmented using CD-ECI include enolate forming phenylglycine containing peptides, glycopeptides, nucleosides, and phosphopeptides. Collision induced dissociation (CID) or other activation techniques were not necessary for CD-ECI fragmentation. A four step mechanism was proposed: (1) complexation using either Fe in the SS capillary tip material or Cu(II) as an offline complexation reagent; (2) electrochemical oxidation of the complexed metal and thus formation of a radical cation (e.g.; Fe − e− → Fe+); (3) radical fragmentation of the complexed compound; (4) electrospray ionization of the fragmented neutrals. Fragmentation patterns resembling b- and y-type ions were observed and allowed the localization of the phosphorylation sites." @default.
• W2016072028 created "2016-06-24" @default.
• W2016072028 creator A5057728137 @default.
• W2016072028 creator A5075072986 @default.
• W2016072028 date "2010-12-01" @default.
• W2016072028 modified "2023-09-26" @default.
• W2016072028 title "Peptide fragmentation by corona discharge induced electrochemical ionization" @default.
• W2016072028 cites W1585900762 @default.
• W2016072028 cites W1963794151 @default.
• W2016072028 cites W1975308470 @default.
• W2016072028 cites W1982326372 @default.
• W2016072028 cites W1988717490 @default.
• W2016072028 cites W1988766191 @default.
• W2016072028 cites W1993652628 @default.
• W2016072028 cites W1999137475 @default.
• W2016072028 cites W1999365897 @default.
• W2016072028 cites W1999674030 @default.
• W2016072028 cites W2002466676 @default.
• W2016072028 cites W2003380203 @default.
• W2016072028 cites W2011568569 @default.
• W2016072028 cites W2013984919 @default.
• W2016072028 cites W2014553645 @default.
• W2016072028 cites W2019639324 @default.
• W2016072028 cites W2023232013 @default.
• W2016072028 cites W2033566010 @default.
• W2016072028 cites W2041651069 @default.
• W2016072028 cites W2043315390 @default.
• W2016072028 cites W2048271426 @default.
• W2016072028 cites W2048346691 @default.
• W2016072028 cites W2048847153 @default.
• W2016072028 cites W2056958151 @default.
• W2016072028 cites W2064140463 @default.
• W2016072028 cites W2065980454 @default.
• W2016072028 cites W2068869943 @default.
• W2016072028 cites W2070591816 @default.
• W2016072028 cites W2073401456 @default.
• W2016072028 cites W2073911018 @default.
• W2016072028 cites W2075478628 @default.
• W2016072028 cites W2076968234 @default.
• W2016072028 cites W2077277234 @default.
• W2016072028 cites W2081056215 @default.
• W2016072028 cites W2081742188 @default.
• W2016072028 cites W2087386675 @default.
• W2016072028 cites W2087563124 @default.
• W2016072028 cites W2095979357 @default.
• W2016072028 cites W2097913561 @default.
• W2016072028 cites W2114175457 @default.
• W2016072028 cites W2121177691 @default.
• W2016072028 cites W2131741443 @default.
• W2016072028 cites W2136035880 @default.
• W2016072028 cites W2136485787 @default.
• W2016072028 cites W2138789091 @default.
• W2016072028 cites W2143340505 @default.
• W2016072028 cites W2153028657 @default.
• W2016072028 cites W2155976322 @default.
• W2016072028 cites W2162590970 @default.
• W2016072028 cites W2335117233 @default.
• W2016072028 doi "https://doi.org/10.1016/j.jasms.2010.08.018" @default.
• W2016072028 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/2991398" @default.
• W2016072028 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20869880" @default.
• W2016072028 hasPublicationYear "2010" @default.
• W2016072028 type Work @default.
• W2016072028 sameAs 2016072028 @default.
• W2016072028 citedByCount "7" @default.
• W2016072028 countsByYear W20160720282012 @default.
• W2016072028 countsByYear W20160720282014 @default.
• W2016072028 countsByYear W20160720282016 @default.
• W2016072028 countsByYear W20160720282017 @default.
• W2016072028 crossrefType "journal-article" @default.
• W2016072028 hasAuthorship W2016072028A5057728137 @default.
• W2016072028 hasAuthorship W2016072028A5075072986 @default.
• W2016072028 hasBestOaLocation W20160720282 @default.
• W2016072028 hasConcept C102931765 @default.
• W2016072028 hasConcept C111919701 @default.
• W2016072028 hasConcept C113196181 @default.
• W2016072028 hasConcept C145148216 @default.
• W2016072028 hasConcept C147789679 @default.
• W2016072028 hasConcept C17525397 @default.
• W2016072028 hasConcept C178790620 @default.
• W2016072028 hasConcept C185592680 @default.
• W2016072028 hasConcept C191015642 @default.
• W2016072028 hasConcept C194451485 @default.
• W2016072028 hasConcept C198291218 @default.
• W2016072028 hasConcept C32909587 @default.
• W2016072028 hasConcept C40684141 @default.
• W2016072028 hasConcept C40875361 @default.
• W2016072028 hasConcept C41008148 @default.
• W2016072028 hasConcept C43617362 @default.
• W2016072028 hasConcept C52859227 @default.
• W2016072028 hasConceptScore W2016072028C102931765 @default.
• W2016072028 hasConceptScore W2016072028C111919701 @default.
• W2016072028 hasConceptScore W2016072028C113196181 @default.
• W2016072028 hasConceptScore W2016072028C145148216 @default.
• W2016072028 hasConceptScore W2016072028C147789679 @default.
• W2016072028 hasConceptScore W2016072028C17525397 @default.
• W2016072028 hasConceptScore W2016072028C178790620 @default.
• W2016072028 hasConceptScore W2016072028C185592680 @default.
• W2016072028 hasConceptScore W2016072028C191015642 @default.

• next