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- W2016075828 abstract "Abstract We studied 0.2 mol dm −3 acetonitrile solutions of 1:1 Be(AuCl 4 ) 2 complexes of cis-1,2-bis-(2-naphthiridine di-N-oxide) ethylene and 1:2 Be(AuCl 4 ) 2 complexes of 1,2-bis-dimethylaminomethyl N-oxide) benzene by FTIR spectroscopy. One Be 2+ ion interacts with four O-atoms of the N-oxide groups as indicated by complete vanishing of the ν(NO) bands. Intense continua indicate that the Be 2+ ions fluctuate between these four acceptor groups in a four-minima Be 2+ potential with relatively steep slopes at the acceptor groups. The Be 2+ ions can relatively easily be shifted within these complexes. They show large “Be 2+ polarizability”." @default.
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- W2016075828 date "1991-03-01" @default.
- W2016075828 modified "2023-10-18" @default.
- W2016075828 title "Fluctuation of Be2+ between four N-oxide acceptors and the polarizability caused by the Be2+ motion" @default.
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- W2016075828 doi "https://doi.org/10.1016/0009-2614(91)87045-d" @default.
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