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- W2016078412 abstract "The unique structural property which links these two molecular solids is the eight membered puckered ring molecule. The molecular orbitals and the energy level schemes that have been proposed are briefly discussed. Electron and hole transport in Sα and Seα is compared on the basis of the available drift mobility data. It is concluded that in both crystals holes propagate in a band with a lattice mobility of about 10 cm2 s−1 V−1. The same applies to electrons in Seα, but the intermolecular electron hopping transport in Sα presents an interesting anomaly, unexpected in view of the structural and electronic similarity of these solids. On the optical side, new reflectivity results for Seα are presented, together with the optical constants between 2 and 14 eV obtained by a Kramers-Krönig analysis. The spectral features of the ε2 curves for Sα and Seα are discussed and the comparison suggests that in Seα a higher lying band (possibly formed from σ and δ orbitals) overlaps the electron hopping level, whereas in Sα it does not. This model also explains the transport problem." @default.
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- W2016078412 date "1972-01-01" @default.
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- W2016078412 title "A comparison of the electronic structure and properties of orthorhombic sulphur and monoclinic selenium" @default.
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- W2016078412 doi "https://doi.org/10.1016/s0022-3697(72)80267-1" @default.
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