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- W2016080370 abstract "We have determined the isotope effects of 17O and 18O substitution of 16O in H2O on molecular diffusivities of water vapor in air by the use of evaporation experiments. The derived diffusion fractionation coefficients 17αdiff and 18αdiff are 1.0146 ± 0.0002 and 1.0283 ± 0.0003, respectively. We also determined, for the first time, the ratio ln(17αdiff)/ln(18αdiff) as 0.5185 ± 0.0002. This ratio, which is in excellent agreement with the theoretical value of 0.5184, is significantly smaller than the ratio in vapor-liquid equilibrium (0.529). We show how this new experimental information gives rise to 17O excess in meteoric water, and how it can be applied in isotope hydrology. Copyright © 2007 John Wiley & Sons, Ltd." @default.
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- W2016080370 date "2007-01-01" @default.
- W2016080370 modified "2023-09-30" @default.
- W2016080370 title "Diffusivity fractionations of H216O/H217O and H216O/H218O in air and their implications for isotope hydrology" @default.
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- W2016080370 doi "https://doi.org/10.1002/rcm.3180" @default.
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