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• W2016085538 startingPage "4359" @default.
• W2016085538 abstract "A bioorganometallic compound GPhAuPPh3 composed of the guanosine and alkynyl-Au(I)PPh3 moieties was prepared. The self-assembly properties in both the absence and presence of KPF6 or La(OTf)3 were studied by NMR, UV-vis, CD and fluorescence measurements. When monovalent KPF6 was added, the expected octamer was formed without any Au(I)–Au(I) interactions. This is due to the presence of the bulky phosphine moiety that makes the Au(I) moieties far away each other. In contrast, in the presence of trivalent La(OTf)3, a more closely stacked octamer was obtained than in the presence of KPF6, leading to Au(I)–Au(I) interactions." @default.
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• W2016085538 date "2012-01-01" @default.
• W2016085538 modified "2023-10-05" @default.
• W2016085538 title "La(OTf)3-mediated self-organization of guanosine with an alkynyl-Au(i)PPh3 moiety to induce Au(i)–Au(i) interactions" @default.
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• W2016085538 doi "https://doi.org/10.1039/c2ra01196d" @default.
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