FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2016086850> ?p ?o ?g. }

• W2016086850 endingPage "183" @default.
• W2016086850 startingPage "176" @default.
• W2016086850 abstract "Catalyst precursors 1 and 2, made by ion-pairing [H3Ru4(CO)12] � with NR þ 4 groups of functionalized MCM-41 and water-soluble poly(diallyldimethylammonium chloride), PDADMAC, respectively, have been evaluated for the chemoselective hydrogenation of nitro- and cyano-benzaldehydes. They are found to be inert toward –NO2 and –CN groups, but active for the reduction of –CHO and >C=C< functionalities. Thus, 3, 4-nitrobenzaldehyde, nitrostyrene, and 3-cyanobenzaldehyde are hydrogenated with full selectivity to the corresponding nitrobenzylalcohols, 1-ethyl-3-nitrobenzene, and 3-cynaobenzylalcohol, respectively. No such chemoselectivity is observed either with PDADMAC-RuCl4 (3) or with (5%)RuAl2O3, where both the functional groups are hydrogenated. Kinetic analyses have been carried out for the hydrogenation of 4-nitrobenzaldehyde with 2. Existence of an induction time and two competitive equilibriums followed by the product-forming rate-determining step are inferred from the empirically derived rate expression. The kinetic results, structural evidences, and previous work strongly suggest that the observed chemoselectivity is probably a result of the absence of multiple crystal planes, differing in Miller indices, in the cluster-derived catalysts." @default.
• W2016086850 created "2016-06-24" @default.
• W2016086850 creator A5012161630 @default.
• W2016086850 creator A5019059433 @default.
• W2016086850 creator A5041733122 @default.
• W2016086850 creator A5044826392 @default.
• W2016086850 creator A5062826786 @default.
• W2016086850 date "2011-12-01" @default.
• W2016086850 modified "2023-10-11" @default.
• W2016086850 title "Control of chemoselectivity in hydrogenations of substituted nitro- and cyano-aromatics by cluster-derived ruthenium nanocatalysts" @default.
• W2016086850 cites W1975500052 @default.
• W2016086850 cites W1983659117 @default.
• W2016086850 cites W1991336871 @default.
• W2016086850 cites W2002501218 @default.
• W2016086850 cites W2006255560 @default.
• W2016086850 cites W2007815917 @default.
• W2016086850 cites W2012930143 @default.
• W2016086850 cites W2014193965 @default.
• W2016086850 cites W2024451528 @default.
• W2016086850 cites W2029048916 @default.
• W2016086850 cites W2031253911 @default.
• W2016086850 cites W2031497013 @default.
• W2016086850 cites W2032719353 @default.
• W2016086850 cites W2034424458 @default.
• W2016086850 cites W2034818269 @default.
• W2016086850 cites W2037119520 @default.
• W2016086850 cites W2040083220 @default.
• W2016086850 cites W2048793284 @default.
• W2016086850 cites W2054658492 @default.
• W2016086850 cites W2055438639 @default.
• W2016086850 cites W2060732588 @default.
• W2016086850 cites W2073772278 @default.
• W2016086850 cites W2079968673 @default.
• W2016086850 cites W2095347012 @default.
• W2016086850 cites W2116809311 @default.
• W2016086850 cites W2128247899 @default.
• W2016086850 cites W2128558863 @default.
• W2016086850 cites W2130936748 @default.
• W2016086850 cites W2133022989 @default.
• W2016086850 cites W2140586100 @default.
• W2016086850 cites W2141215178 @default.
• W2016086850 cites W2143985107 @default.
• W2016086850 cites W2157871632 @default.
• W2016086850 cites W2163640465 @default.
• W2016086850 cites W2319146824 @default.
• W2016086850 cites W2950231949 @default.
• W2016086850 cites W2952197153 @default.
• W2016086850 cites W98766028 @default.
• W2016086850 doi "https://doi.org/10.1016/j.jcat.2011.09.020" @default.
• W2016086850 hasPublicationYear "2011" @default.
• W2016086850 type Work @default.
• W2016086850 sameAs 2016086850 @default.
• W2016086850 citedByCount "14" @default.
• W2016086850 countsByYear W20160868502012 @default.
• W2016086850 countsByYear W20160868502014 @default.
• W2016086850 countsByYear W20160868502016 @default.
• W2016086850 countsByYear W20160868502017 @default.
• W2016086850 countsByYear W20160868502019 @default.
• W2016086850 countsByYear W20160868502020 @default.
• W2016086850 countsByYear W20160868502022 @default.
• W2016086850 countsByYear W20160868502023 @default.
• W2016086850 crossrefType "journal-article" @default.
• W2016086850 hasAuthorship W2016086850A5012161630 @default.
• W2016086850 hasAuthorship W2016086850A5019059433 @default.
• W2016086850 hasAuthorship W2016086850A5041733122 @default.
• W2016086850 hasAuthorship W2016086850A5044826392 @default.
• W2016086850 hasAuthorship W2016086850A5062826786 @default.
• W2016086850 hasConcept C161790260 @default.
• W2016086850 hasConcept C164866538 @default.
• W2016086850 hasConcept C178790620 @default.
• W2016086850 hasConcept C185592680 @default.
• W2016086850 hasConcept C190667039 @default.
• W2016086850 hasConcept C199360897 @default.
• W2016086850 hasConcept C21951064 @default.
• W2016086850 hasConcept C2780263894 @default.
• W2016086850 hasConcept C2780639532 @default.
• W2016086850 hasConcept C41008148 @default.
• W2016086850 hasConcept C45083100 @default.
• W2016086850 hasConcept C555196967 @default.
• W2016086850 hasConceptScore W2016086850C161790260 @default.
• W2016086850 hasConceptScore W2016086850C164866538 @default.
• W2016086850 hasConceptScore W2016086850C178790620 @default.
• W2016086850 hasConceptScore W2016086850C185592680 @default.
• W2016086850 hasConceptScore W2016086850C190667039 @default.
• W2016086850 hasConceptScore W2016086850C199360897 @default.
• W2016086850 hasConceptScore W2016086850C21951064 @default.
• W2016086850 hasConceptScore W2016086850C2780263894 @default.
• W2016086850 hasConceptScore W2016086850C2780639532 @default.
• W2016086850 hasConceptScore W2016086850C41008148 @default.
• W2016086850 hasConceptScore W2016086850C45083100 @default.
• W2016086850 hasConceptScore W2016086850C555196967 @default.
• W2016086850 hasIssue "2" @default.
• W2016086850 hasLocation W20160868501 @default.
• W2016086850 hasOpenAccess W2016086850 @default.
• W2016086850 hasPrimaryLocation W20160868501 @default.
• W2016086850 hasRelatedWork W1977578571 @default.
• W2016086850 hasRelatedWork W2016086850 @default.
• W2016086850 hasRelatedWork W2043012559 @default.

• next